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C1=CC=C(C(=C1)N)NCC(F)(F)F製品情報
2-N-(2,2,2-trifluoroethyl)benzene-1,2-diamine (CAS 1152594-19-8) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
想定用途
専門的研究・工業用途限定
データベース ID 43115453
安全上の注意
For professional research and industrial use only. Review the supplier safety data sheet before handling.
合成データ
8 反応 · 8 文献
反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-0aadfb272b794f5a984a84b8caca5816反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-0aadfb272b794f5a984a84b8caca5816反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-0aadfb272b794f5a984a84b8caca5816反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of (2-nitro-phenyl)-(2,2,2-trifluoro-ethyl)-amine (2.16 g, 9.8 mmol) in THF (6 mL) and MeOH (24 mL) at 0° C. was added ammonium formate (2.47 g, 39.2 mmol). The resulting mixture was purged with nitrogen, then 10% Pd/C (57 mg) was added. The ice bath was removed and the resulting mixture was stirred at room temperature for 5 h. The resulting mixture was filtered over CELITE®, washing with EtOAc. Removal of the solvent in vacuo yielded N-(2,2,2-trifluoro-ethyl)-benzene-1,2-diamine, which was used in the next step without further purification. MS 191 (M+1)+ The resulting mixture was purged with nitrogen 10% Pd/C (57 mg) was added The ice bath was removed The resulting mixture was filtered over CELITE® washing with EtOAc Removal of the solvent in vacuo
ソース ID: ord-3cc607ae678441aa8acd38e459424f1b反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of (2-nitro-phenyl)-(2,2,2-trifluoro-ethyl)-amin (2.16 g, 9.8 mmol) in THF (6 mL) and MeOH (24 mL) at 0° C. was added ammonium formate (2.47 g, 39.2 mmol). The resulting mixture was purged with nitrogen, then 10% Pd/C (57 mg) was added. The ice bath was removed and the reaction mixture was stirred at room temperature for 5 h. The resulting mixture was filtered over CELITE®, washing with EtOAc. Removal of the solvent in vacuo yield N-(2,2,2-trifluoro-ethyl)-benzene-1,2-diamine, which was used in the next step without further purification. MS 191 (M+1)+. The resulting mixture was purged with nitrogen 10% Pd/C (57 mg) was added The ice bath was removed The resulting mixture was filtered over CELITE® washing with EtOAc Removal of the solvent in vacuo
ソース ID: ord-e207f0cfe68846b88b73e207c79fdad2反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of (2-nitro-phenyl)-(2,2,2-trifluoro-ethyl)-amin (2.16 g, 9.8 mmol) in THF (6 mL) and MeOH (24 mL) at 0° C. was added ammonium formate (2.47 g, 39.2 mmol). The resulting mixture was purged with nitrogen, then 10% Pd/C (57 mg) was added. The ice bath was removed and the reaction mixture was stirred at room temperature for 5 h. The resulting mixture was filtered over CELITE®, washing with EtOAc. Removal of the solvent in vacuo yield N-(2,2,2-trifluoro-ethyl)-benzene-1,2-diamine, which was used in the next step without further purification. MS 191 (M+1)+. The resulting mixture was purged with nitrogen 10% Pd/C (57 mg) was added The ice bath was removed The resulting mixture was filtered over CELITE® washing with EtOAc Removal of the solvent in vacuo
ソース ID: ord-6ee3787449d34390a90831c53de26813反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of (2-nitro-phenyl)-(2,2,2-trifluoro-ethyl)-amine (2.16 g, 9.8 mmol) in THF (6 mL) and MeOH (24 mL) at 0° C. was added ammonium formate (2.47 g, 39.2 mmol). The resulting mixture was purged with nitrogen, then 10% Pd/C (57 mg) was added. The ice bath was removed and the resulting mixture was stirred at room temperature for 5 h. The resulting mixture was filtered over CELITE®, washing with EtOAc. Removal of the solvent in vacuo yielded N-(2,2,2-trifluoro-ethyl)-benzene-1,2-diamine, which was used in the next step without further purification. MS 191 (M+1)+ The resulting mixture was purged with nitrogen 10% Pd/C (57 mg) was added The ice bath was removed The resulting mixture was filtered over CELITE® washing with EtOAc Removal of the solvent in vacuo
ソース ID: ord-3cc607ae678441aa8acd38e459424f1b反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of (2-nitro-phenyl)-(2,2,2-trifluoro-ethyl)-amin (2.16 g, 9.8 mmol) in THF (6 mL) and MeOH (24 mL) at 0° C. was added ammonium formate (2.47 g, 39.2 mmol). The resulting mixture was purged with nitrogen, then 10% Pd/C (57 mg) was added. The ice bath was removed and the reaction mixture was stirred at room temperature for 5 h. The resulting mixture was filtered over CELITE®, washing with EtOAc. Removal of the solvent in vacuo yield N-(2,2,2-trifluoro-ethyl)-benzene-1,2-diamine, which was used in the next step without further purification. MS 191 (M+1)+. The resulting mixture was purged with nitrogen 10% Pd/C (57 mg) was added The ice bath was removed The resulting mixture was filtered over CELITE® washing with EtOAc Removal of the solvent in vacuo
ソース ID: ord-e207f0cfe68846b88b73e207c79fdad2PubChem References
化合物の公開データベース記録に掲載された情報源です。
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