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C=C1CC2CCC(C1)C2=O製品情報
3-methylidenebicyclo[3.2.1]octan-8-one (CAS 121506-80-7) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
想定用途
専門的研究・工業用途限定
データベース ID 14174917
安全上の注意
For professional research and industrial use only. Review the supplier safety data sheet before handling.
合成データ
9 反応 · 9 文献
反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-54164ad5c11644d0ace395d9d933c263反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of 3-methylene bicyclo[3,2,1]octan-8-one (0.14 g, 1.04 mmol, 1.0 eq.) in benzene (10 mL) was added ethylene glycol (0.65 g, 16 eq.) and PTSA (0.01 g, 0.06 eq.). The reaction was equipped with a Dean-Stark and heated at reflux overnight. After cooling to room temperature, Et3N (0.15 mL) was introduced and the resulting mixture was passed through a cake of SiO2 and MgSO4. The cake was washed with CH2Cl2 and the combined filtrates were concentrated to give 3-methylene bicyclo[3,2,1]octan-8-one ethylene ketal (0.21 g, >100%). The reaction was equipped with a Dean-Stark heated at reflux overnight The cake was washed with CH2Cl2 the combined filtrates were concentrated
ソース ID: ord-85c5ca4bf8be4d479233261388807431反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of 3-methylene bicyclo[3,2,1]octan-8-one (0.14 g, 1.04 mmol, 1.0 eq.) in benzene (10 mL) was added ethylene glycol (0.65 g, 16 eq.) and PTSA (0.01 g, 0.06 eq.). The reaction was equipped with a Dean-Stark and heated at reflux overnight. After cooling to room temperature, Et3N (0.15 mL) was introduced and the resulting mixture was passed through a cake of SiO2 and MgSO4. The cake was washed with CH2Cl2 and the combined filtrates were concentrated to give 3-methylene bicyclo[3,2,1]octan-8-one ethylene ketal (0.21 g, >100%). The reaction was equipped with a Dean-Stark heated at reflux overnight The cake was washed with CH2Cl2 the combined filtrates were concentrated
ソース ID: ord-85c5ca4bf8be4d479233261388807431反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of 3-methylene bicyclo[3,2,1]octan-8-one (0.14 g, 1.04 mmol, 1.0 eq.) in benzene (10 mL) was added ethylene glycol (0.65 g, 16 eq.) and PTSA (0.01 g, 0.06 eq.). The reaction was equipped with a Dean-Stark and heated at reflux overnight. After cooling to room temperature, Et3N (0.15 mL) was introduced and the resulting mixture was passed through a cake of SiO2 and MgSO4. The cake was washed with CH2Cl2 and the combined filtrates were concentrated to give 3-methylene bicyclo[3,2,1]octan-8-one ethylene ketal (0.21 g, >100%). The reaction was equipped with a Dean-Stark heated at reflux overnight The cake was washed with CH2Cl2 the combined filtrates were concentrated
ソース ID: ord-85c5ca4bf8be4d479233261388807431反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-54164ad5c11644d0ace395d9d933c263反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of 3-methylene bicyclo[3,2,1]octan-8-one (0.14 g, 1.04 mmol, 1.0 eq.) in benzene (10 mL) was added ethylene glycol (0.65 g, 16 eq.) and PTSA (0.01 g, 0.06 eq.). The reaction was equipped with a Dean-Stark and heated at reflux overnight. After cooling to room temperature, Et3N (0.15 mL) was introduced and the resulting mixture was passed through a cake of SiO2 and MgSO4. The cake was washed with CH2Cl2 and the combined filtrates were concentrated to give 3-methylene bicyclo[3,2,1]octan-8-one ethylene ketal (0.21 g, >100%). The reaction was equipped with a Dean-Stark heated at reflux overnight The cake was washed with CH2Cl2 the combined filtrates were concentrated
ソース ID: ord-58a38b810b0347999d790a1f38cb377b反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of 3-methylene bicyclo[3,2,1]octan-8-one (0.14 g, 1.04 mmol, 1.0 eq.) in benzene (10 mL) was added ethylene glycol (0.65 g, 16 eq.) and PTSA (0.01 g, 0.06 eq.). The reaction was equipped with a Dean-Stark and heated at reflux overnight. After cooling to room temperature, Et3N (0.15 mL) was introduced and the resulting mixture was passed through a cake of SiO2 and MgSO4. The cake was washed with CH2Cl2 and the combined filtrates were concentrated to give 3-methylene bicyclo[3,2,1]octan-8-one ethylene ketal (0.21 g, >100%). The reaction was equipped with a Dean-Stark heated at reflux overnight The cake was washed with CH2Cl2 the combined filtrates were concentrated
ソース ID: ord-58a38b810b0347999d790a1f38cb377b反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of 3-methylene bicyclo[3,2,1]octan-8-one (0.14 g, 1.04 mmol, 1.0 eq.) in benzene (10 mL) was added ethylene glycol (0.65 g, 16 eq.) and PTSA (0.01 g, 0.06 eq.). The reaction was equipped with a Dean-Stark and heated at reflux overnight. After cooling to room temperature, Et3N (0.15 mL) was introduced and the resulting mixture was passed through a cake of SiO2 and MgSO4. The cake was washed with CH2Cl2 and the combined filtrates were concentrated to give 3-methylene bicyclo[3,2,1]octan-8-one ethylene ketal (0.21 g, >100%). The reaction was equipped with a Dean-Stark heated at reflux overnight The cake was washed with CH2Cl2 the combined filtrates were concentrated
ソース ID: ord-63e569fe0b6b43e5959bb33c0466ed79反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of 3-methylene bicyclo[3,2,1]octan-8-one (0.14 g, 1.04 mmol, 1.0 eq.) in benzene (10 mL) was added ethylene glycol (0.65 g, 16 eq.) and PTSA (0.01 g, 0.06 eq.). The reaction was equipped with a Dean-Stark and heated at reflux overnight. After cooling to room temperature, Et3N (0.15 mL) was introduced and the resulting mixture was passed through a cake of SiO2 and MgSO4. The cake was washed with CH2Cl2 and the combined filtrates were concentrated to give 3-methylene bicyclo[3,2,1]octan-8-one ethylene ketal (0.21 g, >100%). The reaction was equipped with a Dean-Stark heated at reflux overnight The cake was washed with CH2Cl2 the combined filtrates were concentrated
ソース ID: ord-85c5ca4bf8be4d479233261388807431PubChem References
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