2-(2-sulfanylacetyl)oxyethyl 2-sulfanylacetate

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: GDMA (556.8 g, 5.15 eq.) was weighed into a 2000 ml, three neck, round bottom flask. MAA (442.9 g, 5.15 eq.) and Irgacure 184 (1.5 g) were weighed into a 500 ml addition funnel equipped with a Teflon stop cock.

反応条件: temp:60.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: The flask was set up for reaction and agitation as described in Example 6. No heat was initially added to the flask containing the GDMA. The addition funnel containing the 3-methyl-3-butene-1-ol was placed on the second neck of the flask and a slow drip was started. The reaction exotherm was mild and the addition was completed in 40 minutes. The flask was then heated to 60° C. and held for one hour. Iodine titration indicated a significant amount of free thiol remaining (3.72 meq/g). Lupersol 575 (2.5 g) was added slowly. A significant exotherm occurred, after which the free thiol was measured to be 0.047 meq/gram. The material was then stored in dark high density polyethylene bottles. The flask was set up for reaction and agitation No heat was initially added to the flask the addition held for one hour

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Styrene (481.4 g, 4.62 eq.) was weighed into a 2000 ml, three neck, round bottom flask along with TPO (1.52 g). The flask was sealed with rubber stoppers and placed in a 60° C. oven for approximately 20 minutes. The contents were swirled occasionally until the TPO dissolved into the styrene. The flask was removed from the oven and allowed to cool to less than 40° C. at which point GDMA (518.6 g, 4.467 eq.) was weighed into the flask. The flask was sealed with rubber stoppers placed in a 60° C. for approximately 20 minutes The flask was removed from the oven

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: GDMA (556.8 g, 5.15 eq.) was weighed into a 2000 ml, three neck, round bottom flask. MAA (442.9 g, 5.15 eq.) and Irgacure 184 (1.5 g) were weighed into a 500 ml addition funnel equipped with a Teflon stop cock.

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: GDMA (556.8 g, 5.15 eq.) was weighed into a 2000 ml, three neck, round bottom flask. MAA (442.9 g, 5.15 eq.) and Irgacure 184 (1.5 g) were weighed into a 500 ml addition funnel equipped with a Teflon stop cock.

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Styrene (481.4 g, 4.62 eq.) was weighed into a 2000 ml, three neck, round bottom flask along with TPO (1.52 g). The flask was sealed with rubber stoppers and placed in a 60° C. oven for approximately 20 minutes. The contents were swirled occasionally until the TPO dissolved into the styrene. The flask was removed from the oven and allowed to cool to less than 40° C. at which point GDMA (518.6 g, 4.467 eq.) was weiched into the flask. The flask was sealed with rubber stoppers placed in a 60° C. for approximately 20 minutes The flask was removed from the oven

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: GDMA (556.8 g, 5.15 eq.) was weighed into a 2000 ml, three neck, round bottom flask. MAA (442.9 g, 5.15 eq.) and Irgacure 184 (1.5 g) were weighed into a 500 ml addition funnel equipped with a Teflon stop cock.

反応条件: temp:60.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: The flask was set up for reaction and agitation as described in Example 6. No heat was initially added to the flask containing the GDMA. The addition funnel containing the 3-methyl-3-butene-1-ol was placed on the second neck of the flask and a slow drip was started. The reaction exotherm was mild and the addition was completed in 40 minutes. The flask was then heated to 60° C. and held for one hour. Iodine titration indicated a significant amount of free thiol remaining (3.72 meq/g). Lupersol 575 (2.5 g) was added slowly. A significant exotherm occurred, after which the free thiol was measured to be 0.047 meq/gram. The material was then stored in dark high density polyethylene bottles. The flask was set up for reaction and agitation No heat was initially added to the flask the addition held for one hour

反応条件: temp:60.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: The flask was set up for reaction and agitation as described in Example 6. No heat was initially added to the flask containing the GDMA. The addition funnel containing the 3-methyl-3-butene-1-ol was placed on the second neck of the flask and a slow drip was started. The reaction exotherm was mild and the addition was completed in 40 minutes. The flask was then heated to 60° C. and held for one hour. Iodine titration indicated a significant amount of free thiol remaining (3.72 meq/g). Lupersol 575 (2.5 g) was added slowly. A significant exotherm occurred, after which the free thiol was measured to be 0.047 meq/gram. The material was then stored in dark high density polyethylene bottles. The flask was set up for reaction and agitation No heat was initially added to the flask the addition held for one hour

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Styrene (481.4 g, 4.62 eq.) was weighed into a 2000 ml, three neck, round bottom flask along with TPO (1.52 g). The flask was sealed with rubber stoppers and placed in a 60° C. oven for approximately 20 minutes. The contents were swirled occasionally until the TPO dissolved into the styrene. The flask was removed from the oven and allowed to cool to less than 40° C. at which point GDMA (518.6 g, 4.467 eq.) was weighed into the flask. The flask was sealed with rubber stoppers placed in a 60° C. for approximately 20 minutes The flask was removed from the oven

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: GDMA (556.8 g, 5.15 eq.) was weighed into a 2000 ml, three neck, round bottom flask. MAA (442.9 g, 5.15 eq.) and Irgacure 184 (1.5 g) were weighed into a 500 ml addition funnel equipped with a Teflon stop cock.

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Styrene (481.4 g, 4.62 eq.) was weighed into a 2000 ml, three neck, round bottom flask along with TPO (1.52 g). The flask was sealed with rubber stoppers and placed in a 60° C. oven for approximately 20 minutes. The contents were swirled occasionally until the TPO dissolved into the styrene. The flask was removed from the oven and allowed to cool to less than 40° C. at which point GDMA (518.6 g, 4.467 eq.) was weiched into the flask. The flask was sealed with rubber stoppers placed in a 60° C. for approximately 20 minutes The flask was removed from the oven