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C1=CC=C(C=C1)CN=CC2=CC=CC=C2O製品情報
2-(benzyliminomethyl)phenol (CAS 129855-29-4) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
想定用途
専門的研究・工業用途限定
データベース ID 71643
安全上の注意
For professional research and industrial use only. Review the supplier safety data sheet before handling.
合成データ
12 反応 · 12 文献
反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-2ab6ba81821b42c68b60f8df89d25c66反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-e0b62d382abb43bd9e675e1bd735f479反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: This compound was prepared from 2.7 g of 2-hydroxy-5-methoxy-benzaldehyde, 2.3 mL of benzylamine and 0.03 g of p-toluenesulphonic acid using the procedure described for 64a. Yield: 4:3 g (oil).
ソース ID: ord-9a275bf7cc864595a16b0d6ee571150c反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: Sodium borohydride (0.2 g) was added in small portions to 3 mL of dry 2-propanol in a nitrogen atmosphere. To this mixture was added dropwise a solution of 1.0 g of 2-(benzylimino-methyl)-phenol in 3 mL of 2-propanol. After complete addition, stirring was continued for 1 h. Then water was added in order to decompose excess borohydride, and the volatiles were removed in vacuo. The residue was redissolved in ethyl acetate, washed with water, dried (sodium sulfate) and concentrated yielding 0.9 g of 2-(benzylamino-methyl)-phenol as an oil. EI-MS: 213 (M+). After complete addition the volatiles were removed in vacuo The residue was redissolved in ethyl acetate washed with water dried (sodium sulfate) concentrated
ソース ID: ord-6c93f9cb25fe4e1da7bc99a37d5557d1反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: Sodium borohydride (0.2 g) was added in small portions to 3 mL of dry 2-propanol in a nitrogen atmosphere. To this mixture was added dropwise a solution of 1.0 g of 2-(benzylimino-methyl)-phenol in 3 mL of 2-propanol. After complete addition, stirring was continued for 1 h. Then water was added in order to decompose excess borohydride, and the volatiles were removed in vacuo. The residue was redissolved in ethyl acetate, washed with water, dried (sodium sulfate) and concentrated yielding 0.9 g of 2-(benzylamino-methyl)-phenol as an oil. EI-MS: 213 (M+). After complete addition the volatiles were removed in vacuo The residue was redissolved in ethyl acetate washed with water dried (sodium sulfate) concentrated
ソース ID: ord-6c93f9cb25fe4e1da7bc99a37d5557d1反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: A mixture of 5.0 mL of 2-hydroxy-benzaldehyde, 6.3 mL of benzylamine and 0.05 g of p-toluenesulphonic acid was refluxed in toluene for 2 hours using a Dean-Stark trap to remove liberated water. The volatiles were removed in vacuo yielding 10.1 g of crude 2-(benzylimino-methyl)-phenol to remove liberated water The volatiles were removed in vacuo
ソース ID: ord-affc3acba4bf49088ca5ffae9dd847d4反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: This compound was prepared from 2.7 g of 2-hydroxy-5-methoxy-benzaldehyde, 2.3 mL of benzylamine and 0.03 g of p-toluenesulphonic acid using the procedure described for 64a. Yield: 4.3 g (oil).
ソース ID: ord-d0b227a7913f4de890cf6d104fc511d6反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: Sodium borohydride (0.2 g) was added in small portions to 3 mL of dry 2-propanol in a nitrogen atmosphere. To this mixture was added dropwise a solution of 1.0 g of 2-(benzylimino-methyl)-phenol in 3 mL of 2-propanol. After complete addition, stirring was continued for 1 h. Then water was added in order to decompose excess borohydride, and the volatiles were removed in vacuo. The residue was redissolved in ethyl acetate, washed with water, dried (sodium sulfate) and concentrated yielding 0.9 g of 2-(benzylamino-methyl)-phenol as an oil. EI-MS: 213 (M+). After complete addition the volatiles were removed in vacuo The residue was redissolved in ethyl acetate washed with water dried (sodium sulfate) concentrated
ソース ID: ord-e5c58b6a217b48718b255c5b288ea419反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: Sodium borohydride (0.2 g) was added in small portions to 3 mL of dry 2-propanol in a nitrogen atmosphere. To this mixture was added dropwise a solution of 1.0 g of 2-(benzylimino-methyl)-phenol in 3 mL of 2-propanol. After complete addition, stirring was continued for 1 h. Then water was added in order to decompose excess borohydride, and the volatiles were removed in vacuo. The residue was redissolved in ethyl acetate, washed with water, dried (sodium sulfate) and concentrated yielding 0.9 g of 2-(benzylamino-methyl)-phenol as an oil. EI-MS: 213 (M+). After complete addition the volatiles were removed in vacuo The residue was redissolved in ethyl acetate washed with water dried (sodium sulfate) concentrated
ソース ID: ord-e5c58b6a217b48718b255c5b288ea419反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: A mixture of 5.0 mL of 2-hydroxy-benzaldehyde, 6.3 mL of benzylamine and 0.05 g of p-toluenesulphonic acid was refluxed in toluene for 2 hours using a Dean-Stark trap to remove liberated water. The volatiles were removed in vacuo yielding 10.1 g of crude 2-(benzylimino-methyl)-phenol. to remove liberated water The volatiles were removed in vacuo
ソース ID: ord-f2746416d45a48fb96a40d3ce0b856cd反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-2ab6ba81821b42c68b60f8df89d25c66反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-e0b62d382abb43bd9e675e1bd735f479PubChem References
化合物の公開データベース記録に掲載された情報源です。