aluminum;prop-2-enoate

反応条件: temp:32.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Into the flask described hereinabove there were placed 204.2 grams of aluminium tri-isopropanolate to which 216 grams of acrylic acid were added during 8 minutes at room temperature (25° C.). The procedure was as set forth hereinabove. Owing to the reaction heat, the temperature increased to 32° C. The resultant product was a white, solid substance. The rotary evaporator heating then was switched on and gradually heated to 70° C. At the same time the vacuum was gradually adjusted to 24 mbar. The isopropanol was thereby expelled yielding a white powder. were added during 8 minutes at room temperature (25° C.) Owing to the reaction heat The rotary evaporator heating gradually heated to 70° C The isopropanol was thereby expelled yielding a white powder

反応条件: temp:53.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Into the flask described hereinabove there were placed 102.1 g of aluminium triisopropanolate, 120.1 g of diethylene glycol monobutyl ether, and 0.7 g of 4-methoxyphenol. To this mixture there were added in drops using a dropping funnel 108 grams of acrylic acid. The acid was added during 15 minutes at room temperature (25° C.). Owing to the reaction heat, the temperature increased to 53° C. The mixture was cooled to 39° C. using a water bath. The product remained liquid and stable so that it could be further treated as follows, namely it was heated to 60° C. during 30 minutes and the co-product isopropanol was expelled during 2 hours using a continuous vacuum up to 243 mbar. To this mixture there were added in drops The acid was added during 15 minutes at room temperature (25° C.) Owing to the reaction heat The mixture was cooled to 39° C. stable so that it could be further treated namely it was heated to 60° C. during 30 minutes

反応条件: temp:53.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Into the flask described hereinabove there were placed 102.1 g of aluminium triisopropanolate, 120.1 g of diethylene glycol monobutyl ether, and 0.7 g of 4-methoxyphenol. To this mixture there were added in drops using a dropping funnel 108 grams of acrylic acid. The acid was added during 15 minutes at room temperature (25° C.). Owing to the reaction heat, the temperature increased to 53° C. The mixture was cooled to 39° C. using a water bath. The product remained liquid and stable so that it could be further treated as follows, namely it was heated to 60° C. during 30 minutes and the co-product isopropanol was expelled during 2 hours using a continuous vacuum up to 243 mbar. To this mixture there were added in drops The acid was added during 15 minutes at room temperature (25° C.) Owing to the reaction heat The mixture was cooled to 39° C. stable so that it could be further treated namely it was heated to 60° C. during 30 minutes

反応条件: temp:32.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Into the flask described hereinabove there were placed 204.2 grams of aluminium tri-isopropanolate to which 216 grams of acrylic acid were added during 8 minutes at room temperature (25° C.). The procedure was as set forth hereinabove. Owing to the reaction heat, the temperature increased to 32° C. The resultant product was a white, solid substance. The rotary evaporator heating then was switched on and gradually heated to 70° C. At the same time the vacuum was gradually adjusted to 24 mbar. The isopropanol was thereby expelled yielding a white powder. were added during 8 minutes at room temperature (25° C.) Owing to the reaction heat The rotary evaporator heating gradually heated to 70° C The isopropanol was thereby expelled yielding a white powder

反応条件: temp:53.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Into the flask described hereinabove there were placed 102.1 g of aluminium triisopropanolate, 120.1 g of diethylene glycol monobutyl ether, and 0.7 g of 4-methoxyphenol. To this mixture there were added in drops using a dropping funnel 108 grams of acrylic acid. The acid was added during 15 minutes at room temperature (25° C.). Owing to the reaction heat, the temperature increased to 53° C. The mixture was cooled to 39° C. using a water bath. The product remained liquid and stable so that it could be further treated as follows, namely it was heated to 60° C. during 30 minutes and the co-product isopropanol was expelled during 2 hours using a continuous vacuum up to 243 mbar. To this mixture there were added in drops The acid was added during 15 minutes at room temperature (25° C.) Owing to the reaction heat The mixture was cooled to 39° C. stable so that it could be further treated namely it was heated to 60° C. during 30 minutes