trichloro(2-cyclohex-3-en-1-ylethyl)silane

反応条件: temp:80.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: A flask equipped with a stirrer, reflux condenser, dropping funnel and thermometer was charged with 121.8 g (0.50 mol) of 4-(2-trichlorosilylethyl)-1-cyclohexene and 0.1 g of a 20 wt % isopropanol solution of chloroplatinic acid, which were heated at 80° C. After the internal temperature became constant, 74.5 g (0.55 mol) of trichlorosilane was added dropwise over 10 hours. After the completion of addition, the reaction solution was stirred for 8 hours at 80° C. The reaction solution was distilled, collecting 157.3 g of (2-trichlorosilylethyl)trichlorosilylcyclohexane as a fraction having a boiling point of 122-126° C./0.1 mmHg (yield 83.0%). A flask equipped with a stirrer reflux condenser After the completion of addition The reaction solution was distilled collecting 157.3 g of (2-trichlorosilylethyl)trichlorosilylcyclohexane as a fraction

反応条件: temp:80.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: A flask equipped with a stirrer, reflux condenser, dropping funnel and thermometer was charged with 121.8 g (0.50 mol) of 4-(2-trichlorosilylethyl)-1-cyclohexene and 0.1 g of a 20 wt % isopropanol solution of chloroplatinic acid, which were heated at 80° C. After the internal temperature became constant, 74.5 g (0.55 mol) of trichlorosilane was added dropwise over 10 hours. After the completion of addition, the reaction solution was stirred for 8 hours at 80° C. The reaction solution was distilled, collecting 157.3 g of (2-trichlorosilylethyl)trichlorosilylcyclohexane as a fraction having a boiling point of 122-126° C./0.1 mmHg (yield 83.0%). A flask equipped with a stirrer reflux condenser After the completion of addition The reaction solution was distilled collecting 157.3 g of (2-trichlorosilylethyl)trichlorosilylcyclohexane as a fraction