Zinchydroxide

反応条件: temp:20.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 1,145 parts of stearic acid is added to 5,000 parts of ethanol, and the mixture is mixed at 75° C. 200 parts of zinc hydroxide is added thereto in small amounts, and the mixture is mixed for one hour from the point of completion of introduction. After the mixing, the mixture is cooled to 20° C., and the product is separated by filtration to remove ethanol and reaction residues. The solid product taken therefrom is dried for 3 hours at 150° C. using a heating type vacuum dryer. The product is removed from the dryer and is cooled naturally. Thus, solid zinc stearate is obtained. the mixture is mixed at 75° C in small amounts, and the mixture is mixed for one hour from the point of completion of introduction the product is separated by filtration to remove ethanol and reaction residues The solid product taken therefrom is dried for 3 hours at 150° C. The product is removed from the dryer is cooled naturally

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: A stirred mixture of zinc hydroxide (4.48 g, 45 mmol) and L-lysine (13.45 g, 92 mmol) in ethanol (300 mL) was refluxed for 4 h (became very thick and required mechanical stirring). The above mixture was cooled to room temperature and filtered (slowly), collected, and dried in vacuo. The wet solid was triturated from acetonitrile and dried to afford 14.80 g (92%) of zinc bis-lysinate as a white powder. was refluxed for 4 h ( filtered (slowly), collected dried in vacuo The wet solid was triturated from acetonitrile dried

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: The zinc hydroxide precipitate was then placed into a beaker provided with a reflux condenser and 29.2 grams (0.2 Mole) of lysine was added. 100 ml ethanol was then added to this mixture and stirred and boiled at atmospheric pressure for 3 hours. The reaction mixture was then cooled and filtered yielding 35.5 grams of zinc lysinate in the form of a fine white powder. provided with a reflux condenser The reaction mixture was then cooled filtered

反応条件: temp:20.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 1,145 parts of stearic acid is added to 5,000 parts of ethanol, and the mixture is mixed at 75° C. 200 parts of zinc hydroxide is added thereto in small amounts, and the mixture is mixed for one hour from the point of completion of introduction. After the mixing, the mixture is cooled to 20° C., and the product is separated by filtration to remove ethanol and reaction residues. The solid product taken therefrom is dried for 3 hours at 150° C. using a heating type vacuum dryer. The product is removed from the dryer and is cooled naturally. Thus, solid zinc stearate is obtained. the mixture is mixed at 75° C in small amounts, and the mixture is mixed for one hour from the point of completion of introduction the product is separated by filtration to remove ethanol and reaction residues The solid product taken therefrom is dried for 3 hours at 150° C. The product is removed from the dryer is cooled naturally

反応条件: temp:20.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 1,145 parts of stearic acid is added to 5,000 parts of ethanol, and the mixture is mixed at 75° C. 200 parts of zinc hydroxide is added thereto in small amounts, and the mixture is mixed for one hour from the point of completion of introduction. After the mixing, the mixture is cooled to 20° C., and the product is separated by filtration to remove ethanol and reaction residues. The solid product taken therefrom is dried for 3 hours at 150° C. using a heating type vacuum dryer. The product is removed from the dryer and is cooled naturally. Thus, solid zinc stearate is obtained. the mixture is mixed at 75° C in small amounts, and the mixture is mixed for one hour from the point of completion of introduction the product is separated by filtration to remove ethanol and reaction residues The solid product taken therefrom is dried for 3 hours at 150° C. The product is removed from the dryer is cooled naturally

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Stearic acid and palmitic acid were mixed at a mass ratio of 50:50 to prepare a mixture, and zinc hydroxide was mixed and melted with the resulting mixture to be reacted therewith, and then dried to produce particles in which zinc stearate and palmitic acid were dissolved in each other (particle diameter: 11 μm to 23 μm). A part of the particles thus produced was dissolved in a hydrochloric acid-methanol solution, and the product was heated to 80° C. to methylate the stearic acid and palmitic acid. The methylation product was analyzed by gas chromatography to determine the zinc stearate content and the palmitic acid content and to express them in terms of the equivalent ratio of zinc stearate to zinc palmitate, and the ratio was found to be 48:52 (mass ratio). was mixed to be reacted dried

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Stearic acid and palmitic acid were mixed at a mass ratio of 65:35 to prepare a mixture, and zinc hydroxide was mixed and melted with the resulting mixture to be reacted therewith, and then dried to produce particles in which zinc stearate and palmitic acid were dissolved in each other (particle diameter: 11 μm to 23 μm). A part of the particles thus produced was dissolved in a hydrochloric acid-methanol solution, and the product was heated to 80° C. to methylate the stearic acid and palmitic acid. The methylation product was analyzed by gas chromatography to determine the zinc stearate content and the palmitic acid content and to express them in terms of the equivalent ratio of zinc stearate to zinc palmitate, and the ratio was found to be 64:34 (mass ratio). was mixed to be reacted dried

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Stearic acid and palmitic acid were mixed at a mass ratio of 50:50 to prepare a mixture, and zinc hydroxide was mixed and melted with the resulting mixture to be reacted therewith, and then dried to produce particles in which zinc stearate and palmitic acid were dissolved in each other (particle diameter: 11 μm to 23 μm). A part of the particles thus produced was dissolved in a hydrochloric acid-methanol solution, and the product was heated to 80° C. to methylate the stearic acid and palmitic acid. The methylation product was analyzed by gas chromatography to determine the zinc stearate content and the palmitic acid content and to express them in terms of the equivalent ratio of zinc stearate to zinc palmitate, and the ratio was found to be 48:52 (mass ratio). was mixed to be reacted dried

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Stearic acid and palmitic acid were mixed at a mass ratio of 65:35 to prepare a mixture, and zinc hydroxide was mixed and melted with the resulting mixture to be reacted therewith, and then dried to produce particles in which zinc stearate and palmitic acid were dissolved in each other (particle diameter: 11 μm to 23 μm). A part of the particles thus produced was dissolved in a hydrochloric acid-methanol solution, and the product was heated to 80° C. to methylate the stearic acid and palmitic acid. The methylation product was analyzed by gas chromatography to determine the zinc stearate content and the palmitic acid content and to express them in terms of the equivalent ratio of zinc stearate to zinc palmitate, and the ratio was found to be 64:34 (mass ratio). was mixed to be reacted dried

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: In the second precipitation process, a solution of zinc sulfate (0.0163 mol) dissolved in water (100 mL) was added to the mixture of potassium stearate, zinc hydroxide and graphite. This resulted in immediate precipitation of zinc stearate and gave the zinc active mass as a gray precipitate where the zinc stearate, zinc hydroxide and graphite were present as an intimate mixture. This final precipitated mixture was heated to 70° C. and stirred for a further 10 minutes. Upon cessation of stirring, the active mass mixture settled as a uniformly gray material with no stratification consistent with a homogenous mass. After cooling to room temperature, this active mass was filtered and washed with water. The active mass was used immediately without drying.

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 1,422 parts of stearic acid is added to 10,000 parts of ethanol, and mixed together at 75° C. 507 parts of zinc hydroxide is gradually added to the mixture, and is mixed for one hour after completion of the addition. The resultant mixture is cooled to 20° C., and the reaction product is filtered to remove reaction residue and ethanol. The obtained reaction solid product is dried at 150° C. for 3 hours using a heating vacuum drier. The dried product is taken out from the drier, and is allowed to stand for cooling, as a result of which a solid product of zinc stearate is obtained. After the obtained solid product is milled using a jet mill, the milled product is classified using an ELBOW-JET CLASSIFIER (available from Matsubo Corporation), whereby powdery zinc stearate particles 1 having a volume average particle diameter of 9.6 μm are obtained. The classification cut points when the particles are classified using Elbow-jet classifier are shown in Table 1. The particle size distribution (the ratio of particles having a particle diameter of 25 μm or more, and the ratio of particles having a particle diameter of 40 μm or more) of the obtained zinc stearate particles 1 is shown in Table 1. mixed together at 75° C is mixed for one hour after completion of the addition the reaction product is filtered to remove reaction residue and ethanol The obtained reaction solid product is dried at 150° C. for 3 hours for cooling

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: In the second precipitation process, a solution of zinc sulfate (0.0163 mol) dissolved in water (100 mL) was added to the mixture of potassium stearate, zinc hydroxide and graphite. This resulted in immediate precipitation of zinc stearate and gave the zinc active mass as a gray precipitate where the zinc stearate, zinc hydroxide and graphite were present as an intimate mixture. This final precipitated mixture was heated to 70° C. and stirred for a further 10 minutes. Upon cessation of stirring, the active mass mixture settled as a uniformly gray material with no stratification consistent with a homogenous mass. After cooling to room temperature, this active mass was filtered and washed with water. The active mass was used immediately without drying.