1-(bromomethyl)-4-ethoxybenzene

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 31.5 g of 4-(trans-4-n-propylcyclohexyl)-2-bromothiophenol [prepared from 4-(trans-4-n-propylcyclohexyl)-2-bromophenol obtained according to Example 3 by reaction with dimethylthiocarbamoyl chloride, thermal rearrangement and hydrolysis analogously to Organic Syntheses, Volume 51 (1971), pages 139-142] is etherified with 21.5 g of 4-ethoxybenzyl bromide analogously to Example 1(d). There is obtained 40.2 g of 4-(trans-4-n-propylcyclohexyl)-2-bromophenyl-(4-ethoxybenzyl)thioether. obtained thermal rearrangement and hydrolysis analogously to Organic Syntheses, Volume 51 (1971), pages 139-142]

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 31.5 g of 4-(trans-4-n-propylcyclohexyl)-2-bromothiophenol [prepared from 4-(trans-4-n-propylcyclohexyl)-2-bromophenol obtained according to Example 3 by reaction with dimethylthiocarbamoyl chloride, thermal rearrangement and hydrolysis analogously to Organic Syntheses, Volume 51 (1971), pages 139-142] is etherified with 21.5 g of 4-ethoxybenzyl bromide analogously to Example 1(d). There is obtained 40.2 g of 4-(trans-4-n-propylcyclohexyl)-2-bromophenyl-(4-ethoxybenzyl)thioether. obtained thermal rearrangement and hydrolysis analogously to Organic Syntheses, Volume 51 (1971), pages 139-142]

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 31.5 g of 4-(trans-4-n-propylcyclohexyl)-2-bromothiophenol [prepared from 4-(trans-4-n-propylcyclohexyl)-2-bromophenol obtained according to Example 3 by reaction with dimethylthiocarbamoyl chloride, thermal rearrangement and hydrolysis analogously to Organic Syntheses, Volume 51 (1971), pages 139-142] is etherified with 21.5 g of 4-ethoxybenzyl bromide analogously to Example 1(d). There is obtained 40.2 g of 4-(trans-4-n-propylcyclohexyl)-2-bromophenyl-(4-ethoxybenzyl)thioether. obtained thermal rearrangement and hydrolysis analogously to Organic Syntheses, Volume 51 (1971), pages 139-142]