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C1=CC=C(C=C1)COC2=CC=CC=C2C(=O)N製品情報
2-(Benzyloxy)benzamide (CAS 29579-11-1) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
想定用途
専門的研究・工業用途限定
データベース ID 296051
安全上の注意
For professional research and industrial use only. Review the supplier safety data sheet before handling.
合成データ
10 反応 · 10 文献
反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-54a09e2abc85487f9559e2a95603970c反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-54a09e2abc85487f9559e2a95603970c反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: In a Soxhlet apparatus 18.4 g of lithium aluminium hydride in 1800 ml of dry ether are boiled under a nitrogen atmosphere at a bath temperature of 70°, 5.3 g of 2-benzyloxybenzamide being introduced into the Soxhlet thimble. After 21 hours the reaction mixture is immersed in an ice bath, and 18.4 ml of water, 18.4 ml of 15% sodium hydroxide solution and 55 ml of water are added dropwise in succession, whilst stirring. The temperature may be allowed to rise to a maximum of +10°. Stirring of the mixture is then continued at 20° and the resulting precipitate is suction-filtered and washed with ether. The filtrate is concentrated by evaporation in vacuo and the oil remaining is stirred with 500 ml of 10% hydrochloric acid and 400 ml of ether for 2 hours, whilst cooling with ice. The precipitated 2-benzyloxybenzylamine hydrochloride is suction-filtered, washed with water and ether and dried in vacuo. Melting point 190°-191°. to rise to a maximum of +10° Stirring of the mixture is then continued at 20° the resulting precipitate is suction-filtered washed with ether The filtrate is concentrated by evaporation in vacuo the oil remaining is stirred with 500 ml of 10% hydrochloric acid and 400 ml of ether for 2 hours whilst cooling with ice The precipitated 2-benzyloxybenzylamine hydrochloride is suction-filtered washed with water and ether dried in vacuo
ソース ID: ord-51eced5a435444eeba42ffd4adbf1420反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: In a Soxhlet apparatus 18.4 g of lithium aluminium hydride in 1800 ml of dry ether are boiled under a nitrogen atmosphere at a bath temperature of 70°, 5.3 g of 2-benzyloxybenzamide being introduced into the Soxhlet thimble. After 21 hours the reaction mixture is immersed in an ice bath, and 18.4 ml of water, 18.4 ml of 15% sodium hydroxide solution and 55 ml of water are added dropwise in succession, whilst stirring. The temperature may be allowed to rise to a maximum of +10°. Stirring of the mixture is then continued at 20° and the resulting precipitate is suction-filtered and washed with ether. The filtrate is concentrated by evaporation in vacuo and the oil remaining is stirred with 500 ml of 10% hydrochloric acid and 400 ml of ether for 2 hours, whilst cooling with ice. The precipitated 2-benzyloxybenzylamine hydrochloride is suction-filtered, washed with water and ether and dried in vacuo. Melting point 190°-191°. to rise to a maximum of +10° Stirring of the mixture is then continued at 20° the resulting precipitate is suction-filtered washed with ether The filtrate is concentrated by evaporation in vacuo the oil remaining is stirred with 500 ml of 10% hydrochloric acid and 400 ml of ether for 2 hours whilst cooling with ice The precipitated 2-benzyloxybenzylamine hydrochloride is suction-filtered washed with water and ether dried in vacuo
ソース ID: ord-51eced5a435444eeba42ffd4adbf1420反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: In a Soxhlet apparatus 18.4 g of lithium aluminium hydride in 1800 ml of dry ether are boiled under a nitrogen atmosphere at a bath temperature of 70°, 5.3 g of 2-benzyloxybenzamide being introduced into the Soxhlet thimble. After 21 hours the reaction mixture is immersed in an ice bath, and 18.4 ml of water, 18.4 ml of 15% sodium hydroxide solution and 55 ml of water are added dropwise in succession, whilst stirring. The temperature may be allowed to rise to a maximum of +10°. Stirring of the mixture is then continued at 20° and the resulting precipitate is suction-filtered and washed with ether. The filtrate is concentrated by evaporation in vacuo and the oil remaining is stirred with 500 ml of 10% hydrochloric acid and 400 ml of ether for 2 hours, whilst cooling with ice. The precipitated 2-benzyloxybenzylamine hydrochloride is suction-filtered, washed with water and ether and dried in vacuo. Melting point 190°-191°. to rise to a maximum of +10° Stirring of the mixture is then continued at 20° the resulting precipitate is suction-filtered washed with ether The filtrate is concentrated by evaporation in vacuo the oil remaining is stirred with 500 ml of 10% hydrochloric acid and 400 ml of ether for 2 hours whilst cooling with ice The precipitated 2-benzyloxybenzylamine hydrochloride is suction-filtered washed with water and ether dried in vacuo
ソース ID: ord-9a75a0960f6d4dac9a13d4dd7bfc16cb反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: In a Soxhlet apparatus 18.4 g of lithium aluminium hydride in 1800 ml of dry ether are boiled under a nitrogen atmosphere at a bath temperature of 70°, 5.3 g of 2-benzyloxybenzamide being introduced into the Soxhlet thimble. After 21 hours the reaction mixture is immersed in an ice bath, and 18.4 ml of water, 18.4 ml of 15% sodium hydroxide solution and 55 ml of water are added dropwise in succession, whilst stirring. The temperature may be allowed to rise to a maximum of +10°. Stirring of the mixture is then continued at 20° and the resulting precipitate is suction-filtered and washed with ether. The filtrate is concentrated by evaporation in vacuo and the oil remaining is stirred with 500 ml of 10% hydrochloric acid and 400 ml of ether for 2 hours, whilst cooling with ice. The precipitated 2-benzyloxybenzylamine hydrochloride is suction-filtered, washed with water and ether and dried in vacuo. Melting point 190°-191°. to rise to a maximum of +10° Stirring of the mixture is then continued at 20° the resulting precipitate is suction-filtered washed with ether The filtrate is concentrated by evaporation in vacuo the oil remaining is stirred with 500 ml of 10% hydrochloric acid and 400 ml of ether for 2 hours whilst cooling with ice The precipitated 2-benzyloxybenzylamine hydrochloride is suction-filtered washed with water and ether dried in vacuo
ソース ID: ord-da6fedaf49bb44f0a01d1ff0ecf5e09e反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: In a Soxhlet apparatus 18.4 g of lithium aluminium hydride in 1800 ml of dry ether are boiled under a nitrogen atmosphere at a bath temperature of 70°, 5.3 g of 2-benzyloxybenzamide being introduced into the Soxhlet thimble. After 21 hours the reaction mixture is immersed in an ice bath, and 18.4 ml of water, 18.4 ml of 15% sodium hydroxide solution and 55 ml of water are added dropwise in succession, whilst stirring. The temperature may be allowed to rise to a maximum of +10°. Stirring of the mixture is then continued at 20° and the resulting precipitate is suction-filtered and washed with ether. The filtrate is concentrated by evaporation in vacuo and the oil remaining is stirred with 500 ml of 10% hydrochloric acid and 400 ml of ether for 2 hours, whilst cooling with ice. The precipitated 2-benzyloxybenzylamine hydrochloride is suction-filtered, washed with water and ether and dried in vacuo. Melting point 190°-191°. to rise to a maximum of +10° Stirring of the mixture is then continued at 20° the resulting precipitate is suction-filtered washed with ether The filtrate is concentrated by evaporation in vacuo the oil remaining is stirred with 500 ml of 10% hydrochloric acid and 400 ml of ether for 2 hours whilst cooling with ice The precipitated 2-benzyloxybenzylamine hydrochloride is suction-filtered washed with water and ether dried in vacuo
ソース ID: ord-da6fedaf49bb44f0a01d1ff0ecf5e09e反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: In a Soxhlet apparatus 18.4 g of lithium aluminium hydride in 1800 ml of dry ether are boiled under a nitrogen atmosphere at a bath temperature of 70°, 5.3 g of 2-benzyloxybenzamide being introduced into the Soxhlet thimble. After 21 hours the reaction mixture is immersed in an ice bath, and 18.4 ml of water, 18.4 ml of 15% sodium hydroxide solution and 55 ml of water are added dropwise in succession, whilst stirring. The temperature may be allowed to rise to a maximum of +10°. Stirring of the mixture is then continued at 20° and the resulting precipitate is suction-filtered and washed with ether. The filtrate is concentrated by evaporation in vacuo and the oil remaining is stirred with 500 ml of 10% hydrochloric acid and 400 ml of ether for 2 hours, whilst cooling with ice. The precipitated 2-benzyloxybenzylamine hydrochloride is suction-filtered, washed with water and ether and dried in vacuo. Melting point 190°-191°. to rise to a maximum of +10° Stirring of the mixture is then continued at 20° the resulting precipitate is suction-filtered washed with ether The filtrate is concentrated by evaporation in vacuo the oil remaining is stirred with 500 ml of 10% hydrochloric acid and 400 ml of ether for 2 hours whilst cooling with ice The precipitated 2-benzyloxybenzylamine hydrochloride is suction-filtered washed with water and ether dried in vacuo
ソース ID: ord-51eced5a435444eeba42ffd4adbf1420反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: In a Soxhlet apparatus 18.4 g of lithium aluminium hydride in 1800 ml of dry ether are boiled under a nitrogen atmosphere at a bath temperature of 70°, 5.3 g of 2-benzyloxybenzamide being introduced into the Soxhlet thimble. After 21 hours the reaction mixture is immersed in an ice bath, and 18.4 ml of water, 18.4 ml of 15% sodium hydroxide solution and 55 ml of water are added dropwise in succession, whilst stirring. The temperature may be allowed to rise to a maximum of +10°. Stirring of the mixture is then continued at 20° and the resulting precipitate is suction-filtered and washed with ether. The filtrate is concentrated by evaporation in vacuo and the oil remaining is stirred with 500 ml of 10% hydrochloric acid and 400 ml of ether for 2 hours, whilst cooling with ice. The precipitated 2-benzyloxybenzylamine hydrochloride is suction-filtered, washed with water and ether and dried in vacuo. Melting point 190°-191°. to rise to a maximum of +10° Stirring of the mixture is then continued at 20° the resulting precipitate is suction-filtered washed with ether The filtrate is concentrated by evaporation in vacuo the oil remaining is stirred with 500 ml of 10% hydrochloric acid and 400 ml of ether for 2 hours whilst cooling with ice The precipitated 2-benzyloxybenzylamine hydrochloride is suction-filtered washed with water and ether dried in vacuo
ソース ID: ord-9a75a0960f6d4dac9a13d4dd7bfc16cb反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: In a Soxhlet apparatus 18.4 g of lithium aluminium hydride in 1800 ml of dry ether are boiled under a nitrogen atmosphere at a bath temperature of 70°, 5.3 g of 2-benzyloxybenzamide being introduced into the Soxhlet thimble. After 21 hours the reaction mixture is immersed in an ice bath, and 18.4 ml of water, 18.4 ml of 15% sodium hydroxide solution and 55 ml of water are added dropwise in succession, whilst stirring. The temperature may be allowed to rise to a maximum of +10°. Stirring of the mixture is then continued at 20° and the resulting precipitate is suction-filtered and washed with ether. The filtrate is concentrated by evaporation in vacuo and the oil remaining is stirred with 500 ml of 10% hydrochloric acid and 400 ml of ether for 2 hours, whilst cooling with ice. The precipitated 2-benzyloxybenzylamine hydrochloride is suction-filtered, washed with water and ether and dried in vacuo. Melting point 190°-191°. to rise to a maximum of +10° Stirring of the mixture is then continued at 20° the resulting precipitate is suction-filtered washed with ether The filtrate is concentrated by evaporation in vacuo the oil remaining is stirred with 500 ml of 10% hydrochloric acid and 400 ml of ether for 2 hours whilst cooling with ice The precipitated 2-benzyloxybenzylamine hydrochloride is suction-filtered washed with water and ether dried in vacuo
ソース ID: ord-da6fedaf49bb44f0a01d1ff0ecf5e09ePubChem References
化合物の公開データベース記録に掲載された情報源です。