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CC1=CC(=CC(=C1N)C)I製品情報
4-iodo-2,6-dimethylaniline (CAS 4102-53-8) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
想定用途
専門的研究・工業用途限定
データベース ID 278942
安全上の注意
For professional research and industrial use only. Review the supplier safety data sheet before handling.
合成データ
8 反応 · 8 文献
反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-fd9fa37b0b224808909b9314a3634713反応条件: temp:0.01; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of 2,6-dimethyl aniline (50 gm) in 1,4-dioxane (400 ml) and pyridine (40 ml) was added iodine (157.3 gm) slowly at 0° C. The solution was stirred for 1 hour at 0° C. and the temperature was raised to room temperature. The solution was stirred for 1 hour at room temperature and then added a saturated solution of sodium thiosulfate. The layers were separated and the aqueous layer was extracted with methylene chloride. The combined organic layers were dried with anhydrous sodium sulfate and the solvent was evaporated in vacuum to obtain 91.8 gm of 4-iodo-2,6-dimethyl benzenamine. the temperature was raised to room temperature The solution was stirred for 1 hour at room temperature The layers were separated the aqueous layer was extracted with methylene chloride The combined organic layers were dried with anhydrous sodium sulfate the solvent was evaporated in vacuum
ソース ID: ord-394692fda96645f988ef30d8fef96a08反応条件: temp:0.01; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of 2,6-dimethyl aniline (50 gm) in 1,4-dioxane (400 ml) and pyridine (40 ml) was added iodine (157.3 gm) slowly at 0° C. The solution was stirred for 1 hour at 0° C. and the temperature was raised to room temperature. The solution was stirred for 1 hour at room temperature and then added a saturated solution of sodium thiosulfate. The layers were separated and the aqueous layer was extracted with methylene chloride. The combined organic layers were dried with anhydrous sodium sulfate and the solvent was evaporated in vacuum to obtain 91.8 gm of 4-iodo-2,6-dimethyl benzenamine. the temperature was raised to room temperature The solution was stirred for 1 hour at room temperature The layers were separated the aqueous layer was extracted with methylene chloride The combined organic layers were dried with anhydrous sodium sulfate the solvent was evaporated in vacuum
ソース ID: ord-394692fda96645f988ef30d8fef96a08反応条件: temp:0.01; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of 2,6-dimethyl aniline (25 gm) in 1,4-dioxane (200 ml) and dimethylacetamide (20 ml) was added iodine (79 gm) slowly at 0° C. The solution was stirred for 1 hour at 0° C. and the temperature was raised to room temperature. The solution was stirred for 1 hour at room temperature and then added a saturated solution of sodium thiosulfate. The layers were separated and the aqueous layer was extracted with methylene chloride. The combined organic layers were dried with anhydrous sodium sulfate and the solvent was evaporated in vacuum to obtain 45 gm of 4-iodo-2,6-dimethyl benzenamine. the temperature was raised to room temperature The solution was stirred for 1 hour at room temperature The layers were separated the aqueous layer was extracted with methylene chloride The combined organic layers were dried with anhydrous sodium sulfate the solvent was evaporated in vacuum
ソース ID: ord-cb9305547de8470f988989b2f585f61f反応条件: temp:0.01; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of 2,6-dimethyl aniline (50 gm) in 1,4-dioxane (400 ml) and N-methylpyrrolidone (40 ml) was added iodine (157.3 gm) slowly at 0° C. The solution was stirred for 1 hour at 0° C. and the temperature was raised to room temperature. The solution was stirred for 1 hour at room temperature and then added a saturated solution of sodium thiosulfate. The layers were separated and the aqueous layer was extracted with methylene chloride. The combined organic layers were dried with anhydrous sodium sulfate and the solvent was evaporated in vacuum to obtain 91 gm of 4-iodo-2,6-dimethyl benzenamine. the temperature was raised to room temperature The solution was stirred for 1 hour at room temperature The layers were separated the aqueous layer was extracted with methylene chloride The combined organic layers were dried with anhydrous sodium sulfate the solvent was evaporated in vacuum
ソース ID: ord-5407fc16acc14e34a5f9995983dc505a反応条件: temp:0.01; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of 2,6-dimethyl aniline (50 gm) in 1,4-dioxane (400 ml) and pyridine (40 ml) was added iodine (157.3 gm) slowly at 0° C. The solution was stirred for 1 hour at 0° C. and the temperature was raised to room temperature. The solution was stirred for 1 hour at room temperature and then added a saturated solution of sodium thiosulfate. The layers were separated and the aqueous layer was extracted with methylene chloride. The combined organic layers were dried with anhydrous sodium sulfate and the solvent was evaporated in vacuum to obtain 91.8 gm of 4-iodo-2,6-dimethyl benzenamine. the temperature was raised to room temperature The solution was stirred for 1 hour at room temperature The layers were separated the aqueous layer was extracted with methylene chloride The combined organic layers were dried with anhydrous sodium sulfate the solvent was evaporated in vacuum
ソース ID: ord-d5508c13a42645a7b39165f3954ffde6反応条件: temp:0.01; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of 2,6-dimethyl aniline (50 gm) in 1,4-dioxane (400 ml) and pyridine (40 ml) was added iodine (157.3 gm) slowly at 0° C. The solution was stirred for 1 hour at 0° C. and the temperature was raised to room temperature. The solution was stirred for 1 hour at room temperature and then added a saturated solution of sodium thiosulfate. The layers were separated and the aqueous layer was extracted with methylene chloride. The combined organic layers were dried with anhydrous sodium sulfate and the solvent was evaporated in vacuum to obtain 91.8 gm of 4-iodo-2,6-dimethyl benzenamine. the temperature was raised to room temperature The solution was stirred for 1 hour at room temperature The layers were separated the aqueous layer was extracted with methylene chloride The combined organic layers were dried with anhydrous sodium sulfate the solvent was evaporated in vacuum
ソース ID: ord-d5508c13a42645a7b39165f3954ffde6反応条件: temp:0.01; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of 2,6-dimethyl aniline (50 gm) in 1,4-dioxane (400 ml) and pyridine (40 ml) was added iodine (157.3 gm) slowly at 0° C. The solution was stirred for 1 hour at 0° C. and the temperature was raised to room temperature. The solution was stirred for 1 hour at room temperature and then added a saturated solution of sodium thiosulfate. The layers were separated and the aqueous layer was extracted with methylene chloride. The combined organic layers were dried with anhydrous sodium sulfate and the solvent was evaporated in vacuum to obtain 91.8 gm of 4-iodo-2,6-dimethyl benzenamine. the temperature was raised to room temperature The solution was stirred for 1 hour at room temperature The layers were separated the aqueous layer was extracted with methylene chloride The combined organic layers were dried with anhydrous sodium sulfate the solvent was evaporated in vacuum
ソース ID: ord-394692fda96645f988ef30d8fef96a08PubChem References
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