Methylsulfonyl acetate

反応条件: temp:25.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: a mixture of 12.7 g of acetyl methanesulfonate and 9.15 g of trioxymethylene diacetate was prepared at 0° C and then stirred at 25° C for 20 hours. Distillation at 10μ produced 4.5 g of CH3SO3CH2OCH2OSO2CH3 b.p. 110°-115° C (pot temp.); m.p. 57°-59° C. was prepared at 0° C Distillation at 10μ

反応条件: temp:25.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: a mixture of 12.7 g of acetyl methanesulfonate and 9.15 g of trioxymethylene diacetate was prepared at 0° C and then stirred at 25° C for 20 hours. Distillation at 10μ produced 4.5 g of CH3SO3CH2OCH2OSO2CH3 b.p. 110°-115° C (pot temp.); m.p. 57°-59° C. was prepared at 0° C Distillation at 10μ

反応条件: temp:25.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: A mixture of 12.7 g of acetyl methanesulfonate and 9.15 g of trioxymethylene diacetate was prepared at 0° C. and then stirred at 25° C. for 20 hours. Distillation at 10μ produced 4.5 g of CH3SO3CH2OCH2OSO2CH3, b.p. 110°-115° C. (pot temp.); m.p. 57°-59° C. was prepared at 0° C. Distillation at 10μ

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Using the procedure of Example 2, acetyl methanesulfonate and tetroxane, in a molar ratio of 2:1, were reacted for 18-24 hours at 90° C. and 0.5 mm. pressure allowing the bis(acetoxymethyl) ether to distill. The residual oil was recrystallized from a small volume of dry tetrahydrofuran to give a 67% yield of CH3SO3CH2OCH2OSO2CH3. in a molar ratio of 2:1, were reacted for 18-24 hours at 90° C. to distill The residual oil was recrystallized from a small volume of dry tetrahydrofuran

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Using the procedure of Example 2, acetyl methanesulfonate and tetroxane, in a molar ratio of 2:1, were reacted for 18-24 hours at 90° C. and 0.5 mm. pressure allowing the bis(acetoxymethyl) ether to distill. The residual oil was recrystallized from a small volume of dry tetrahydrofuran to give a 67% yield of CH3SO3CH2OCH2OSO2CH3. in a molar ratio of 2:1, were reacted for 18-24 hours at 90° C. to distill The residual oil was recrystallized from a small volume of dry tetrahydrofuran

反応条件: temp:25.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: a mixture of 12.7 g of acetyl methanesulfonate and 9.15 g of trioxymethylene diacetate was prepared at 0° C and then stirred at 25° C for 20 hours. Distillation at 10μ produced 4.5 g of CH3SO3CH2OCH2OSO2CH3 b.p. 110°-115° C (pot temp.); m.p. 57°-59° C. was prepared at 0° C Distillation at 10μ