2-phenoxyethyl prop-2-enoate

反応条件: temp:75.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 360.0 g of methyl ethyl ketone was introduced in a 2 L three-necked flask equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen gas introduction tube, and was heated to 75° C. Thereafter, while the temperature inside the flask was maintained at 75° C., a mixture solution of 180.0 g of phenoxyethyl acrylate, 162.0 g of methyl methacrylate, 18.0 g of acrylic acid, 72 g of methyl ethyl ketone, and 1.44 g of “V-601” (trade name, manufactured by Wako Pure Chemical Industries Ltd.) was added dropwise into the flask at a constant rate such that the dropwise addition was completed in 2 hours. After the dropwise addition was completed, a solution of 0.72 g of “V-601 (trade name)” and 36.0 g of methyl ethyl ketone was added into the flask, stirred at 75° C. for 2 hours, and a solution of 0.72 g of V-601 and 36.0 g of isopropanol was further added, and the contents of the flask were stirred at 75° C. for 2 hours. Then, the temperature inside the flask was increased to 85° C., and stirring was continued for another 2 hours. As a result, a resin solution of a copolymer of phenoxyethyl acrylate/methyl methacrylate/acrylic acid (=50/45/5 [mass ratio]) was obtained. equipped with a stirrer Thereafter, while the temperature inside the flask was maintained at 75° C. After the dropwise addition the contents of the flask were stirred at 75° C. for 2 hours Then, the temperature inside the flask was increased to 85° C. stirring was continued for another 2 hours

反応条件: temp:75.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 360.0 g of methyl ethyl ketone was placed in a 2 L three-necked flask equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen gas introduction tube, and was heated to 75° C. Thereafter, while the temperature inside the flask was maintained at 75° C., a mixture solution of 180.0 g of phenoxyethyl acrylate, 162.0 g of methyl methacrylate, 18.0 g of acrylic acid, 72 g of methyl ethyl ketone, and 1.44 g of V-601 (trade name, manufactured by Wako Pure Chemical Industries Ltd.) was added dropwise into the flask at a constant rate such that the dropwise addition was completed in 2 hours. After the dropwise addition was completed, a solution of 0.72 g of V-601 in 36.0 g of methyl ethyl ketone was added into the flask, stirred at 75° C. for 2 hours, and a solution of 0.72 g of V-601 in 36.0 g of isopropanol was further added, and the contents of the flask were stirred at 75° C. for 2 hours. Then, the temperature inside the flask was increased to 85° C., and stirring was continued for another 2 hours. As a result, a resin solution of a copolymer of phenoxyethyl acrylate/methyl methacrylate/acrylic acid (in a ratio of 50/45/5 by mass) was obtained. equipped with a stirrer Thereafter, while the temperature inside the flask was maintained at 75° C. After the dropwise addition the contents of the flask were stirred at 75° C. for 2 hours Then, the temperature inside the flask was increased to 85° C. stirring was continued for another 2 hours

反応条件: temp:75.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 360.0 g of methyl ethyl ketone was added to a 2 liter three-necked flask provided with a stirrer, a thermometer, a reflux condenser, and a nitrogen gas introducing tube, followed by heating up to 75° C. Thereafter, while maintaining the temperature inside the flask at 75° C., a mixed solution of 180.0 g of phenoxyethyl acrylate, 162.0 g of methyl methacrylate, 18.0 g of acrylic acid, 72 g of methyl ethyl ketone, and 1.44 g of “V-601” (manufactured by Wako Pure Chemical Industries, Ltd.) was added dropwise thereto at a constant speed such that the dropwise addition was completed in two hours. After the completion of the dropwise addition, a solution containing 0.72 g of “V-601” and 36.0 g of methyl ethyl ketone was added thereto followed by stirring at 75° C. for 2 hours. Furthermore, a solution containing 0.72 g of “V-601” and 36.0 g of isopropanol was added thereto followed by stirring at 75° C. for 2 hours, and heated to 85° C. followed by stirring for another 2 hours, thereby obtaining a resin solution of a phenoxyethyl acrylate/methyl methacrylate/acrylic acid (=50/45/5 [mass ratio]) copolymer. provided with a stirrer a thermometer, a reflux condenser, and a nitrogen gas introducing tube Thereafter, while maintaining the temperature inside the flask at 75° C. at a constant speed such that the dropwise addition After the completion of the dropwise addition was added was added by stirring at 75° C. for 2 hours heated to 85° C. by stirring for another 2 hours

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: To a reactor, 53.3 parts by mass of bisphenol-A/ethyleneoxide 2 mole-adduct, 34.0 parts by mass of xylylene diisocyanate, and 93.5 parts by mass of phenoxyethyl acrylate were added and reacted at 80° C. for 5 hours; then, 6.2 parts by mass of 2-hydroxyethyl acrylate and 0.03 parts by mass of urethanizing catalyst were added and reacted at 80° C. for 5 hours, to obtain a urethane acrylate-based oligomer (i.e. a light curable oligomer). reacted at 80° C. for 5 hours reacted at 80° C. for 5 hours

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: To a reactor, 53.3 parts by mass of bisphenol-A/ethyleneoxide 2 mole-adduct, 34.0 parts by mass of xylylene diisocyanate, and 93.5 parts by mass of phenoxyethyl acrylate were added and reacted at 80° C. for 5 hours; then, 6.2 parts by mass of 2-hydroxyethyl acrylate and 0.03 parts by mass of urethanizing catalyst were added and reacted at 80° C. for 5 hours, to obtain a urethane acrylate-based oligomer (i.e. a light curable oligomer). reacted at 80° C. for 5 hours reacted at 80° C. for 5 hours

反応条件: temp:75.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 360.0 g of methyl ethyl ketone was introduced in a 2 L three-necked flask equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen gas introduction tube, and was heated to 75° C. Thereafter, while the temperature inside the flask was maintained at 75° C., a mixture solution of 180.0 g of phenoxyethyl acrylate, 162.0 g of methyl methacrylate, 18.0 g of acrylic acid, 72 g of methyl ethyl ketone, and 1.44 g of “V-601” (trade name, manufactured by Wako Pure Chemical Industries Ltd.) was added dropwise into the flask at a constant rate such that the dropwise addition was completed in 2 hours. After the dropwise addition was completed, a solution of 0.72 g of “V-601 (trade name)” and 36.0 g of methyl ethyl ketone was added into the flask, stirred at 75° C. for 2 hours, and a solution of 0.72 g of V-601 and 36.0 g of isopropanol was further added, and the contents of the flask were stirred at 75° C. for 2 hours. Then, the temperature inside the flask was increased to 85° C., and stirring was continued for another 2 hours. As a result, a resin solution of a copolymer of phenoxyethyl acrylate/methyl methacrylate/acrylic acid (=50/45/5 [mass ratio]) was obtained. equipped with a stirrer Thereafter, while the temperature inside the flask was maintained at 75° C. After the dropwise addition the contents of the flask were stirred at 75° C. for 2 hours Then, the temperature inside the flask was increased to 85° C. stirring was continued for another 2 hours

反応条件: temp:75.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 360.0 g of methyl ethyl ketone was introduced in a 2 L three-necked flask equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen gas introduction tube, and was heated to 75° C. Thereafter, while the temperature inside the flask was maintained at 75° C., a mixture solution of 180.0 g of phenoxyethyl acrylate, 162.0 g of methyl methacrylate, 18.0 g of acrylic acid, 72 g of methyl ethyl ketone, and 1.44 g of “V-601” (trade name, manufactured by Wako Pure Chemical Industries Ltd.) was added dropwise into the flask at a constant rate such that the dropwise addition was completed in 2 hours. After the dropwise addition was completed, a solution of 0.72 g of “V-601 (trade name)” and 36.0 g of methyl ethyl ketone was added into the flask, stirred at 75° C. for 2 hours, and a solution of 0.72 g of V-601 and 36.0 g of isopropanol was further added, and the contents of the flask were stirred at 75° C. for 2 hours. Then, the temperature inside the flask was increased to 85° C., and stirring was continued for another 2 hours. As a result, a resin solution of a copolymer of phenoxyethyl acrylate/methyl methacrylate/acrylic acid (=50/45/5 [mass ratio]) was obtained. equipped with a stirrer Thereafter, while the temperature inside the flask was maintained at 75° C. After the dropwise addition the contents of the flask were stirred at 75° C. for 2 hours Then, the temperature inside the flask was increased to 85° C. stirring was continued for another 2 hours

反応条件: temp:75.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 360.0 g of methyl ethyl ketone was placed in a 2 L three-necked flask equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen gas introduction tube, and was heated to 75° C. Thereafter, while the temperature inside the flask was maintained at 75° C., a mixture solution of 180.0 g of phenoxyethyl acrylate, 162.0 g of methyl methacrylate, 18.0 g of acrylic acid, 72 g of methyl ethyl ketone, and 1.44 g of V-601 (trade name, manufactured by Wako Pure Chemical Industries Ltd.) was added dropwise into the flask at a constant rate such that the dropwise addition was completed in 2 hours. After the dropwise addition was completed, a solution of 0.72 g of V-601 in 36.0 g of methyl ethyl ketone was added into the flask, stirred at 75° C. for 2 hours, and a solution of 0.72 g of V-601 in 36.0 g of isopropanol was further added, and the contents of the flask were stirred at 75° C. for 2 hours. Then, the temperature inside the flask was increased to 85° C., and stirring was continued for another 2 hours. As a result, a resin solution of a copolymer of phenoxyethyl acrylate/methyl methacrylate/acrylic acid (in a ratio of 50/45/5 by mass) was obtained. equipped with a stirrer Thereafter, while the temperature inside the flask was maintained at 75° C. After the dropwise addition the contents of the flask were stirred at 75° C. for 2 hours Then, the temperature inside the flask was increased to 85° C. stirring was continued for another 2 hours

反応条件: temp:75.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 360.0 g of methyl ethyl ketone was placed in a 2 L three-necked flask equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen gas introduction tube, and was heated to 75° C. Thereafter, while the temperature inside the flask was maintained at 75° C., a mixture solution of 180.0 g of phenoxyethyl acrylate, 162.0 g of methyl methacrylate, 18.0 g of acrylic acid, 72 g of methyl ethyl ketone, and 1.44 g of V-601 (trade name, manufactured by Wako Pure Chemical Industries Ltd.) was added dropwise into the flask at a constant rate such that the dropwise addition was completed in 2 hours. After the dropwise addition was completed, a solution of 0.72 g of V-601 in 36.0 g of methyl ethyl ketone was added into the flask, stirred at 75° C. for 2 hours, and a solution of 0.72 g of V-601 in 36.0 g of isopropanol was further added, and the contents of the flask were stirred at 75° C. for 2 hours. Then, the temperature inside the flask was increased to 85° C., and stirring was continued for another 2 hours. As a result, a resin solution of a copolymer of phenoxyethyl acrylate/methyl methacrylate/acrylic acid (in a ratio of 50/45/5 by mass) was obtained. equipped with a stirrer Thereafter, while the temperature inside the flask was maintained at 75° C. After the dropwise addition the contents of the flask were stirred at 75° C. for 2 hours Then, the temperature inside the flask was increased to 85° C. stirring was continued for another 2 hours

反応条件: temp:75.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: In a 2-liter three-necked flask equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen gas inlet tube, 360.0 g of methyl ethyl ketone was inserted and the temperature was raised to 75° C. While the temperature inside the flask was maintained at 75° C., a mixed solution containing 180.0 g of phenoxyethyl acrylate, 162.0 g of methyl methacrylate, 18.0 g of acrylic acid, 72 g of methyl ethyl ketone, and 1.44 g of “V-601” (manufactured by Wako Pure Chemical Industries, Ltd.) was added dropwise at a constant rate so that the dropwise addition was completed in 2 hours. After completion of the dropwise addition, a solution containing 0.72 g of “V-601” and 36.0 g of methyl ethyl ketone was added to this, and after the mixture was stirred for 2 hours at 75° C., a solution containing 0.72 g of “V-601” and 36.0 g of isopropanol was added thereto and stirred for 2 hours at 75° C. After this, the temperature was raised to 85° C. and stirring was continued for another 2 hours and a resin solution of a phenoxyethyl acrylate/methyl methacrylate/acrylic acid (=50/45/5 [mass ratio]) copolymer was obtained. In a 2-liter three-necked flask equipped with a stirrer While the temperature inside the flask was maintained at 75° C. was added dropwise at a constant rate so that the dropwise addition After completion of the dropwise addition was added to this, and after the mixture was added stirred for 2 hours at 75° C After this, the temperature was raised to 85° C. stirring was continued for another 2 hours

反応条件: temp:75.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: In a 2-liter three-necked flask equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen gas inlet tube, 360.0 g of methyl ethyl ketone was inserted and the temperature was raised to 75° C. While the temperature inside the flask was maintained at 75° C., a mixed solution containing 180.0 g of phenoxyethyl acrylate, 162.0 g of methyl methacrylate, 18.0 g of acrylic acid, 72 g of methyl ethyl ketone, and 1.44 g of “V-601” (manufactured by Wako Pure Chemical Industries, Ltd.) was added dropwise at a constant rate so that the dropwise addition was completed in 2 hours. After completion of the dropwise addition, a solution containing 0.72 g of “V-601” and 36.0 g of methyl ethyl ketone was added to this, and after the mixture was stirred for 2 hours at 75° C., a solution containing 0.72 g of “V-601” and 36.0 g of isopropanol was added thereto and stirred for 2 hours at 75° C. After this, the temperature was raised to 85° C. and stirring was continued for another 2 hours and a resin solution of a phenoxyethyl acrylate/methyl methacrylate/acrylic acid (=50/45/5 [mass ratio]) copolymer was obtained. In a 2-liter three-necked flask equipped with a stirrer While the temperature inside the flask was maintained at 75° C. was added dropwise at a constant rate so that the dropwise addition After completion of the dropwise addition was added to this, and after the mixture was added stirred for 2 hours at 75° C After this, the temperature was raised to 85° C. stirring was continued for another 2 hours

反応条件: temp:75.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: In a 2-liter three-necked flask equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen gas inlet tube, 360.0 g of methyl ethyl ketone was inserted and the temperature was raised to 75° C. While the temperature inside the flask was maintained at 75° C., a mixed solution containing 180.0 g of phenoxyethyl acrylate, 162.0 g of methyl methacrylate, 18.0 g of acrylic acid, 72 g of methyl ethyl ketone, and 1.44 g of “V-601” (manufactured by Wako Pure Chemical Industries, Ltd.) was added dropwise at a constant rate so that the dropwise addition was completed in 2 hours. After completion of the dropwise addition, a solution containing 0.72 g of “V-601” and 36.0 g of methyl ethyl ketone was added to this, and after the mixture was stirred for 2 hours at 75° C., a solution containing 0.72 g of “V-601” and 36.0 g of isopropanol was added thereto and stirred for 2 hours at 75° C. After this, the temperature was raised to 85° C. and stirring was continued for another 2 hours and a resin solution of a phenoxyethyl acrylate/methyl methacrylate/acrylic acid (=50/45/5 [mass ratio]) copolymer was obtained. In a 2-liter three-necked flask equipped with a stirrer While the temperature inside the flask was maintained at 75° C. was added dropwise at a constant rate so that the dropwise addition After completion of the dropwise addition was added to this, and after the mixture was added stirred for 2 hours at 75° C After this, the temperature was raised to 85° C. stirring was continued for another 2 hours