zinc;diacetate;dihydrate

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: To this wrinkle resistant, durable press fabric was applied a treating solution containing 40.0 parts by weight of zinc acetate dihydrate, 125 parts of 30% aqueous hydrogen peroxide, the amount of glacial acetic acid specified in Table IX and 52.8 parts water. The fabric was immersed and thoroughly wet in the treating solution, and was passed through a wringer having squeeze rolls adjusted to give a wet pickup of 105%-120%. The fabric was heat-cured in a forced-draft oven for 5 min. at 85° C., was afterwards washed for 15 min. in hot running water at 60° C., and was oven-dried for 5 min. at 85° C. The zinc and peroxide content, and fabric performance in the parallel streak test with Staphylococcus aureus, are shown in Table IX. to give a wet pickup of 105%-120% was afterwards washed for 15 min. at 60° C. was oven-dried for 5 min. at 85° C

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: N-Ethyl-N-phenyl-5-ethyl-1,2-dihydro-4-hydroxy-1-methyl-2-oxo-3-quinolinecarboxamide (1.0 g, 2.85 mmol) was dissolved in a mixture of 1M NaOH (2.95 mmol, 2.95 ml) and ethanol (6.0 ml). Chloroform (20 ml) and water (40 ml) were added followed by addition of zinc acetate dihydrate (3.0 mmol, 660 mg). The two-phase mixture was stirred vigorously for 10 min, the organic phase was separated and dried with sodium sulphate and the solvents were removed. The residue was recrystallised from methanol to give the title compound (823 mg, 76% yield). Anal. Calcd for C42H42N4O6Zn: C, 66.01; H, 5.54; N, 7.33. Found C, 65.4; H, 5.68; N, 7.29. EDTA-titriometric determination of zinc gave a content of 8.45% (theoretical content is 8.50%), The solubility in water at room temperature was 0.3 mg/ml. the organic phase was separated dried with sodium sulphate the solvents were removed The residue was recrystallised from methanol

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Zinc acetate dihydrate (1.0 g) was dissolved in 75 ml. of hot methanol and 1.4 g of 8-hydroxyquinoline was added to the homogeneous solution. A yellow precipitate formed after a few minutes and the solution was stirred at reflux for 3 hours. The solution was allowed to cool and the precipitate was isolated by filtration and washed with methanol and petroleum ether. After air drying, 1.44 g of bis(8-hydroxyquinolinato)zinc was obtained as a bright yellow solid. A yellow precipitate formed after a few minutes at reflux for 3 hours to cool the precipitate was isolated by filtration washed with methanol and petroleum ether After air drying

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Zinc acetate dihydrate (1.0 g) was dissolved in 75 ml. of hot methanol and 1.4 g of 8-hydroxyquinoline was added to the homogeneous solution. A yellow precipitate formed after a few minutes and the solution was stirred at reflux for 3 hours. The solution was allowed to cool and the precipitate was isolated by filtration and washed with methanol and petroleum ether. After air drying, 1.44 g of bis(8-hydroxyquinolinato)zinc was obtained as a bright yellow solid. A yellow precipitate formed after a few minutes at reflux for 3 hours to cool the precipitate was isolated by filtration washed with methanol and petroleum ether After air drying

反応条件: temp:120.02; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Anhydrous L-leucine, 5.2472 g, 0.0400 mole, was dissolved in 30 ml of deionized water and heated to 120° F. Ultra-pure zinc acetate dihydrate, Zn(C2H3O2)2.2H2O, 4.3900 g, 0.0200 mole, was added in small increments over one hour, with stirring. The solution did not clear, so another 20 ml of water was added and the mixture was heated in a boiling water bath to 190° F. for an additional 21/2hours. Water was then added to a total volume of 75 ml, the mixture heated again to 190° F., and gravity filtered. The retained solid was dried at 150° F. for 12 hours, found to weigh 2.717 g, and was analyzed. the mixture was heated in a boiling water bath to 190° F. for an additional 21/2hours the mixture heated again to 190° F. gravity filtered The retained solid was dried at 150° F. for 12 hours

反応条件: temp:120.02; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Anhydrous L-leucine, 5.2472 g, 0.0400 mole, was dissolved in 30 ml of deionized water and heated to 120° F. Ultra-pure zinc acetate dihydrate, Zn(C2H3O2)2.2H2O, 4.3900 g, 0.0200 mole, was added in small increments over one hour, with stirring. The solution did not clear, so another 20 ml of water was added and the mixture was heated in a boiling water bath to 190° F. for an additional 21/2hours. Water was then added to a total volume of 75 ml, the mixture heated again to 190° F., and gravity filtered. The retained solid was dried at 150° F. for 12 hours, found to weigh 2.717 g, and was analyzed. the mixture was heated in a boiling water bath to 190° F. for an additional 21/2hours the mixture heated again to 190° F. gravity filtered The retained solid was dried at 150° F. for 12 hours

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: N-Ethyl-N-phenyl- 5-ethyl- 1,2-dihydro- 4-hydroxy- 1-methyl- 2-oxo- 3-quinolinecarboxamide ( 1.0 g, 2.85 mmol) was dissolved in a mixture of 1M NaOH ( 2.95 mmol, 2.95 ml) and ethanol ( 6.0 ml). Chloroform ( 20 ml) and water ( 40 ml) were added followed by addition of zinc acetate dihydrate ( 3.0 mmol, 660 mg). The two-phase mixture was stirred vigorously for 10 min, the organic phase was separated and dried with sodium sulphate and the solvents were removed. The residue was recrystallised from methanol to give the title compound ( 823 mg, 76% yield). Anal. Calcd for C42H42N4O6Zn: C, 66.01; H, 5.54; N, 7.33. Found C, 65.4; H, 5.68; N, 7.29. EDTA-titriometric determination of zinc gave a content of 8.45% (theoretical content is 8.56%). the organic phase was separated dried with sodium sulphate the solvents were removed The residue was recrystallised from methanol

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Sodium hydroxide (3.51 g) was dissolved in methanol (100 ml), and L-carnosine (9.96 g) was added to the solution to prepare a uniform solution. A solution with zinc acetate dihydrate (9.67 g) dissolved in methanol (145 ml) was added dropwise over 30 minutes to the uniform solution. As a result, white precipitate was gradually formed. After completion of the addition, the mixture was stirred for 2 hours, left to stand overnight and then filtered. The resultant filter cake was then washed with water (140 ml) and air-dried at 80° C. for 5 hours to obtain a crystalline L-carnosine zinc salt (12.4 g) as white powdery crystals. to prepare a uniform solution was added dropwise over 30 minutes to the uniform solution As a result, white precipitate was gradually formed After completion of the addition left to stand overnight filtered The resultant filter cake was then washed with water (140 ml) air-dried at 80° C. for 5 hours

反応条件: temp:80.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 1.58 g (10.0 mmol) of phenylphosphonic acid (manufactured by Nissan Chemical industries, Ltd.), 2.20 g (10.0 mmol) of zinc acetate dihydrate and 72 g of water were mixed, stirred at 80° C. for 3 hours, then the resulting slurry was filtered, acetic acid in the wet cake was fully washed away with water, and thereafter, dried at 150° C. to obtain 2.17 g (yield 98%) of the aimed product as white crystal. Decomposition temperature: 541° C. The average particle diameter was 4.4 μm with a laser diffraction type particle size distribution meter (manufactured by Seishin Enterprise Co., Ltd., PRO-7000S). the resulting slurry was filtered acetic acid in the wet cake was fully washed away with water dried at 150° C.

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: To a 30 percent w/v aqueous dispersion of the mono-2-ethylhexyl itaconate is added 1 molar equivalent of sodium hydroxide as a 10 percent w/v aqueous solution (800 ml). After the stirred suspension clears, 0.5 molar equivalent (219 g) of zinc acetate dihydrate as a saturated aqueous solution is added with stirring. The supernatant liquid is separated from the precipitated zinc 2-ethylhexyl itaconate (6A). The supernatant liquid is separated from the precipitated zinc 2-ethylhexyl itaconate (6A)

反応条件: temp:50.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: To a 12 percent w/v acetone suspension of the monododecyl fumarate heated to 50° C. is added 1.0 molar equivalent sodium hydroxide (299 g) as a 10 percent w/v aqueous solution. After the stirred suspension clears, 0.5 molar equivalent zinc acetate dihydrate (110 g) as a saturated aqueous solution is added with stirring. The supernatant liquid is separated from the precipitated zinc dodecyl fumarate. The supernatant liquid is separated from the precipitated zinc dodecyl fumarate

反応条件: temp:50.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: To a 12 percent w/v acetone suspension of the monododecyl fumarate heated to 50° C. is added 1.0 molar equivalent sodium hydroxide (299 g) as a 10 percent w/v aqueous solution. After the stirred suspension clears, 0.5 molar equivalent zinc acetate dihydrate (110 g) as a saturated aqueous solution is added with stirring. The supernatant liquid is separated from the precipitated zinc dodecyl fumarate. The supernatant liquid is separated from the precipitated zinc dodecyl fumarate