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C1=CC=C(C(=C1)CCl)CCl製品情報
1,2-bis(chloromethyl)benzene (CAS 612-12-4) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
想定用途
専門的研究・工業用途限定
データベース ID 11919
安全上の注意
For professional research and industrial use only. Review the supplier safety data sheet before handling.
合成データ
12 反応 · 12 文献
反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-d58638a55d374b75982ed18b47ad0ed7反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-0a874389e50c4824973f61f95b162e65反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-470176a5be0945518b0a92cbe9c84ce4反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-44796b2eab7041b49b1a17e3d5b8e7ff反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-b633709eedaa40c8be04fd953c9d40e6反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-a5f454ce64304086a33118c42182face反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: A mixture of tri-n-butylphosphine (18.9 g, 103.8 mmol) in toluene (50 mL) was added dropwise to a mixture of α,α'-dichloro-o-xylene (7.0 g, 34.6 mmol) in toluene (200 mL) under argon gas. The reaction mixture was allowed to stir for several days at room temperature under argon, at which time TLC examination showed completion of reaction. Toluene was removed under reduced pressure to give an oily residue. The above oily residue was washed with toluene/hexane (50/50 (v/v), 4×100 mL), and then dried to give a colorless oil. 1H NMR (CDCl3) δ0.89 (t, 9H), 1.43 (m, 12H), 2.52 (m, 6H), 4.41 (d, 2H), 4.88 (s, 2H), 7.33 (m, 2H), 7.4 5 (m, 1H), 7.52 (m, 1H). completion of reaction Toluene was removed under reduced pressure to give an oily residue The above oily residue was washed with toluene/hexane (50/50 (v/v), 4×100 mL) dried to give a colorless oil
ソース ID: ord-99457bcc819f4162b682d7924cdf7a88反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a mixture of α,α'-dichloro-o-xylene (15.0 g, 86.0 mmol) in toluene (200 ml) was added triethylphosphine (6.3 ml, 43.0 mmol) under argon gas. The reaction mixture was stirred for several days at room temperature under argon after which time the triethylphosphonium chloride salt had crystallized out of solution. The crystals were filtered and washed with toluene (3×50 mL) and pentane (3×50 mL) and dried: 1H NMR (CDCl3) δ1.15-1.26 (dt, 9), 2.58-2.69 (m, 6H), 4.39-4.44 (d, 2H), 4.87 (s, 2H) , 7.31-7.34 (dd, 2H) , 7.43-7.46 (dd, 1H), 7.50-7.54 (m, 1H). had crystallized out of solution The crystals were filtered washed with toluene (3×50 mL) and pentane (3×50 mL) dried
ソース ID: ord-10ae76f6ec0f4443944228377f5b406d反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-d58638a55d374b75982ed18b47ad0ed7反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-0a874389e50c4824973f61f95b162e65反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-0a874389e50c4824973f61f95b162e65反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: A mixture of tri-n-butylphosphine (18.9 g, 103.8 mmol) in toluene (50 mL) was added dropwise to a mixture of α,α'-dichloro-o-xylene (7.0 g, 34.6 mmol) in toluene (200 mL) under argon gas. The reaction mixture was allowed to stir for several days at room temperature under argon, at which time TLC examination showed completion of reaction. Toluene was removed under reduced pressure to give an oily residue. The above oily residue was washed with toluene/hexane (50/50 (v/v), 4×100 mL), and then dried to give a colorless oil. 1H NMR (CDCl3) δ 0.89 (t, 9H), 1.43 (m, 12H), 2.52 (m, 6H), 4.41 (d, 2H), 4.88 (s, 2H), 7.33 (m, 2H), 7.45 (m, 1H), 7.52 (m, 1H). completion of reaction Toluene was removed under reduced pressure to give an oily residue The above oily residue was washed with toluene/hexane (50/50 (v/v), 4×100 mL) dried to give a colorless oil
ソース ID: ord-cdcffba7dce24911a2e8597c5c20513cPubChem References
化合物の公開データベース記録に掲載された情報源です。