表示可能な構造データがありません
CCCCCCCCCCCCCCCCCC=O製品情報
octadecanal (CAS 638-66-4) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
想定用途
専門的研究・工業用途限定
データベース ID 12533
安全上の注意
For professional research and industrial use only. Review the supplier safety data sheet before handling.
合成データ
12 反応 · 12 文献
反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-88129892158141d2ad43c7166ef528e0反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-767b7d6cbbe0445181d57059c47128f5反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a stirred solution of 21 parts of octadecanal in 65 parts of dichloromethane and 50 parts of 1,4-dioxane there were added dropwise 34.1 parts of bromine. After stirring for 4 hours at room temperature, the reaction mixture was poured into 250 parts of water. The product was extracted with dichloromethane and the extract was dried, filtered and evaporated, yielding 28 parts (95%) of 2-bromooctadecanal (interm. 1). The product was extracted with dichloromethane the extract was dried filtered evaporated
ソース ID: ord-4461cb09591f42b5ba3fa0938bb77d41反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a stirred solution of 21 parts of octadecanal in 65 parts of dichloromethane and 50 parts of 1,4-dioxane there were added dropwise 34.1 parts of bromine. After stirring for 4 hours at room temperature, the reaction mixture was poured into 250 parts of water. The product was extracted with dichloromethane and the extract was dried, filtered and evaporated, yielding 28 parts (95%) of 2-bromooctadecanal (interm. 1). The product was extracted with dichloromethane the extract was dried filtered evaporated
ソース ID: ord-4461cb09591f42b5ba3fa0938bb77d41反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a stirred solution of 21 parts of octadecanal in 65 parts of dichloromethane and 50 parts of 1,4-dioxane there were added dropwise 34.1 parts of bromine. After stirring for 4 hours at room temperature, the reaction mixture was poured into 250 parts of water. The product was extracted with dichloromethane and the extract was dried, filtered and evaporated, yielding 28 parts (95%) of 2-bromooctadecanal (interm. 1). The product was extracted with dichloromethane the extract was dried filtered evaporated
ソース ID: ord-70f4f79ae803409e9f48017d82ae7ff2反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a stirred solution of 21 parts of octadecanal in 65 parts of dichloromethane and 50 parts of 1,4-dioxane there were added dropwise 34.1 parts of bromine. After stirring for 4 hours at room temperature, the reaction mixture was poured into 250 parts of water. The product was extracted with dichloromethane and the extract was dried, filtered and evaporated, yielding 28 parts (95%) of 2-bromooctadecanal (interm. 1). The product was extracted with dichloromethane the extract was dried filtered evaporated
ソース ID: ord-70f4f79ae803409e9f48017d82ae7ff2反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of octadecanal (9a) (2.22 g, 8.28 mmol) and nitromethane (1.52 g, 24.90 mmol) in anhyd Et2O (10 mL), Amberlyst A-21 (1.2 g) was added at r.t. The mixture was stirred and heated at reflux for 48 h. After removal of the Amberlyst A-21 by filtration, the filtrate was concentrated under reduced pressure. Flash column chromatography of the residue (EtOAc/petroleum spirit, 5/95) gave 1-nitrononadecan-2-ol (10a) (2.41 g, 89%) as a white solid; mp 55-56° C. heated at reflux for 48 h After removal of the Amberlyst A-21 by filtration the filtrate was concentrated under reduced pressure
ソース ID: ord-1a66b4f4fd6443ebb7a9425d7f95a691反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of octadecanal (9a) (2.22 g, 8.28 mmol) and nitromethane (1.52 g, 24.90 mmol) in anhyd Et2O (10 mL), Amberlyst A-21 (1.2 g) was added at r.t. The mixture was stirred and heated at reflux for 48 h. After removal of the Amberlyst A-21 by filtration, the filtrate was concentrated under reduced pressure. Flash column chromatography of the residue (EtOAc/petroleum spirit, 5/95) gave 1-nitrononadecan-2-ol (10a) (2.41 g, 89%) as a white solid; mp 55-56° C. heated at reflux for 48 h After removal of the Amberlyst A-21 by filtration the filtrate was concentrated under reduced pressure
ソース ID: ord-1a66b4f4fd6443ebb7a9425d7f95a691反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: TZD18 was prepared according to General Procedure A presented hereinabove using 2,4-thiazolidinedione and stearaldehyde as reactants.
ソース ID: ord-c067b3faf9c244e2b9d7bdc5c0587915反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a stirred solution of 21 parts of octadecanal in 65 parts of dichloromethane and 50 parts of 1,4-dioxane there were added dropwise 34.1 parts of bromine. After stirring for 4 hours at room temperature, the reaction mixture was poured into 250 parts of water. The product was extracted with dichloromethane and the extract was dried, filtered and evaporated, yielding 28 parts (95%) of 2-bromooctadecanal (interm. 1). The product was extracted with dichloromethane the extract was dried filtered evaporated
ソース ID: ord-4461cb09591f42b5ba3fa0938bb77d41反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a stirred solution of 21 parts of octadecanal in 65 parts of dichloromethane and 50 parts of 1,4-dioxane there were added dropwise 34.1 parts of bromine. After stirring for 4 hours at room temperature, the reaction mixture was poured into 250 parts of water. The product was extracted with dichloromethane and the extract was dried, filtered and evaporated, yielding 28 parts (95%) of 2-bromooctadecanal (interm. 1). The product was extracted with dichloromethane the extract was dried filtered evaporated
ソース ID: ord-70f4f79ae803409e9f48017d82ae7ff2反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-88129892158141d2ad43c7166ef528e0PubChem References
化合物の公開データベース記録に掲載された情報源です。