2-[difluoro(methoxy)methyl]-1,1,1,3,3,3-hexafluoropropane

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: (CF3)2CHCF2OCH3 (ether A, 7.1 g) and a solution of (CF3)2CHCO2H (0.6 g) in water (10 mL) are independently and continuously fed to the reactor over 5 hours. The reactor is preheated to 450° C. and maintained at this temperature throughout the run. The reactor pressure is maintained at about atmospheric pressure. The reactor effluent is scrubbed to remove HF. The product includes CF3CH=CF2 (HFC-1225zc) and HFC-236fa. is preheated to 450° C. maintained at this temperature throughout the run The reactor pressure is maintained at about atmospheric pressure to remove HF

反応条件: temp:175.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Activated carbon (25 g, 1/8" (0.32 mm) diameter pellets) and deionized water (24.4 g) are loaded into a 1" (2.54 cm) OD×12" (30.5 cm) length Inconel™ 600 nickel alloy tube. The reactor temperature is raised to 175° C. and the reactor pressure adjusted to 30 psig (310 kPa). (CF3)2CHCF2OCH3 (ether A, 21.0 g) and a solution of (CF3)2CHCO2H (1.8 g) in water (10 mL) are independently and continuously fed to the reactor over 5 hours. The reactor effluent is scrubbed to remove HF. The product includes HFC-236fa and CF3CH=CF2 (HFC-1225zc) . to remove HF

反応条件: temp:250.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Activated carbon (25 g, 1/8" (0.32 mm) diameter pellets) and deionized water (20 g) are loaded into a 1" (2.54 cm) OD×12" (30.5 cm) length Inconel™ 600 nickel alloy tube. The reactor temperature is raised to 250° C. and the reactor pressure adjusted to 0 psig (101 kPa). (CF3)2CHCF2OCH3 (ether A, 21.5 g) and a solution of (CF3)2CHCO2H (1.8 g) in water (10 mL) and tetrahydrofuran (20 mL) are independently and continuously fed to the reactor over 5 hours. The reactor effluent is scrubbed to remove HF. The product includes HFC-236fa and CF3CH=CF2 (HFC-1225zc). to remove HF

反応条件: temp:250.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Activated carbon (25 g, 1/8" (0.32 mm) diameter pellets) and deionized water (5.3 g) are loaded into a 1" (2.54 cm) OD×12" (30.5 cm) length Inconel™ 600 nickel alloy tube. The reactor temperature is raised to 250° C. and the reactor pressure adjusted to 150 psig (1140 kPa). (CF3)2CHCF2OCH3 (ether A, 21.1 g) and a solution of (CF3)2CHCO2H (1.8 g) in water (10 mL) are independently and continuously fed to the reactor over 5 hours. The reactor effluent is scrubbed to remove HF. The product includes HFC-236fa and CF3CH=CF2 (HFC-1225zc) . to remove HF

反応条件: temp:350.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Activated carbon (25 g, 1/8" (0.32 mm) diameter pellets) and deionized water (10 g) are loaded into a 1" (2.54 cm) OD×12" (30.5 cm) length Inconel™ 600 nickel alloy tube. The reactor temperature is raised to 350° C. and the reactor pressure adjusted to 0 psig (101 kPa). (CF3)2CHCF2OCH3 (ether A, 53.4 g) and a solution of (CF3)2CHCO2H (4.5 g) in water (10 mL) are independently and continuously fed to the reactor over 5 hours. After the feed flow is stopped, the reactor is flushed with deionized water (10 g). The reactor effluent is scrubbed to remove HF. The product includes HFC-236fa and CF3CH=CF2 (HFC-1225zc). the reactor is flushed with deionized water (10 g) to remove HF

反応条件: temp:280.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Activated carbon (25 g, 1/8" (0.32 mm) diameter pellets) and deionized water (5.8 g) are loaded into a 1" (2.54 cm) OD×12" (30.5 cm) length Inconel™ 600 nickel alloy tube. The reactor temperature is raised to 280° C. and the reactor pressure adjusted to 230 psig (1690 kPa). (CF3)2CHCF2OCH3 (ether A, 6.8 g) and a solution of (CF3)2CHCO2H (1.5 g) in water (10 mL) are independently and continuously fed to the reactor over 3 hours. After the feed flow is stopped, the reactor is flushed with deionized water (11.2 g) . The reactor effluent is scrubbed to remove HF. The product includes HFC-236fa and CF3CH=CF2 (HFC-1225zc). the reactor is flushed with deionized water (11.2 g) to remove HF

反応条件: temp:320.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Activated carbon (25 g, 1/8" (0.32 mm) diameter pellets) and deionized water (5 g) are loaded into a 1" (2.54 cm) OD×12" (30.5 cm) length Inconel™ 600 nickel alloy tube. The reactor temperature is raised to 320° C. and the reactor pressure adjusted to 230 psig (1690 kPa). (CF3)2CHCF2OCH3 (ether A, 9.2 g) and a solution of (CF3)2CHCO2H (2.0 g) in water (6 mL) are independently and continuously fed to the reactor over 3 hours. After the feed flow is stopped, the reactor is flushed with deionized water (10 g) . The reactor effluent is scrubbed to remove HF. The product includes both HFC-236fa and CF3CH=CF2 (HFC-1225zc). the reactor is flushed with deionized water (10 g) to remove HF

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: A 100 g mixture containing 59.0% (CF3)2CHCF2OCH3 (ether A), 20% (CF3)2C=CFOCH3 (ether B), 15.9% toluene and 150 mL water was heated in a Hastelloy™ nickel alloy tube for 3 hours at 135° C. and 6 hours at 200° C. The volatiles were bubbled through a solution of aqueous NaOH and a CaSO4 drying column, and condensed in a dry ice cooled trap to give 12.9 g HFC-236fa identified by its infrared spectrum. The liquid contents of the tube contained two layers. The upper layer, 14.9 g, was shown by 1H and 19F NMR spectroscopy to contain 16.5 wt. percent HFC-236fa and toluene. The combined HFC-236fa from the volatiles and the toluene corresponded to a yield of 15.4 g, 29.0% based on the starting ethers. The volatiles were bubbled through a solution of aqueous NaOH a CaSO4 drying column, and condensed in a dry ice cooled trap

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: (CF3)2CHCF2OCH3 (ether A, 7.1 g) and a solution of (CF3)2CHCO2H (0.6 g) in water (10 mL) are independently and continuously fed to the reactor over 5 hours. The reactor is preheated to 450° C. and maintained at this temperature throughout the run. The reactor pressure is maintained at about atmospheric pressure. The reactor effluent is scrubbed to remove HF. The product includes CF3CH=CF2 (HFC-1225zc) and HFC-236fa. is preheated to 450° C. maintained at this temperature throughout the run The reactor pressure is maintained at about atmospheric pressure to remove HF

反応条件: temp:175.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Activated carbon (25 g, 1/8" (0.32 mm) diameter pellets) and deionized water (24.4 g) are loaded into a 1" (2.54 cm) OD×12" (30.5 cm) length Inconel™ 600 nickel alloy tube. The reactor temperature is raised to 175° C. and the reactor pressure adjusted to 30 psig (310 kPa). (CF3)2CHCF2OCH3 (ether A, 21.0 g) and a solution of (CF3)2CHCO2H (1.8 g) in water (10 mL) are independently and continuously fed to the reactor over 5 hours. The reactor effluent is scrubbed to remove HF. The product includes HFC-236fa and CF3CH=CF2 (HFC-1225zc) . to remove HF

反応条件: temp:250.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Activated carbon (25 g, 1/8" (0.32 mm) diameter pellets) and deionized water (20 g) are loaded into a 1" (2.54 cm) OD×12" (30.5 cm) length Inconel™ 600 nickel alloy tube. The reactor temperature is raised to 250° C. and the reactor pressure adjusted to 0 psig (101 kPa). (CF3)2CHCF2OCH3 (ether A, 21.5 g) and a solution of (CF3)2CHCO2H (1.8 g) in water (10 mL) and tetrahydrofuran (20 mL) are independently and continuously fed to the reactor over 5 hours. The reactor effluent is scrubbed to remove HF. The product includes HFC-236fa and CF3CH=CF2 (HFC-1225zc). to remove HF

反応条件: temp:250.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Activated carbon (25 g, 1/8" (0.32 mm) diameter pellets) and deionized water (5.3 g) are loaded into a 1" (2.54 cm) OD×12" (30.5 cm) length Inconel™ 600 nickel alloy tube. The reactor temperature is raised to 250° C. and the reactor pressure adjusted to 150 psig (1140 kPa). (CF3)2CHCF2OCH3 (ether A, 21.1 g) and a solution of (CF3)2CHCO2H (1.8 g) in water (10 mL) are independently and continuously fed to the reactor over 5 hours. The reactor effluent is scrubbed to remove HF. The product includes HFC-236fa and CF3CH=CF2 (HFC-1225zc) . to remove HF