[dimethyl(trimethylsilyloxy)silyl] acetate

反応条件: temp:0.00; pressure:0.00; stir:

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: This monomer was prepared in a manner similar to that described in Example 1. The reactants were γ-methacryloxypropyltrimethoxysilane (2 moles), 1,3-Bis(acetoxy)-1,1,3,3-TETRA(trimethylsiloxy)disiloxane (1 mole) and acetoxypentamethyldisiloxane (4 moles). This material is designated SM-16. This monomer was prepared in a manner similar to

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: This monomer was prepared in a manner similar to that described in Example 1. The reactants were γ-methacryloxypropyltrimethoxysilane (2 moles), 1,3-Bis(acetoxy)-1,1,3,3-TETRA(trimethylsiloxy)disiloxane (1 mole) and acetoxypentamethyldisiloxane (4 moles). This material is designated SM-16. This monomer was prepared in a manner similar to

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: This monomer was prepared in a manner similar to that described in Example 1. The reactants were γ-methacryloxypropyltrimethoxysilane (2 moles), 1,3-Bis(acetoxy)-1,1,3,3-TETRA(trimethylsiloxy)disiloxane (1 mole) and acetoxypentamethyldisiloxane (4 moles). This material is designated SM-16. This monomer was prepared in a manner similar to

反応条件: temp:0.00; pressure:0.00; stir:

反応条件: temp:105.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: A mixture containing 14.8 g of 1,1,1,3,3-pentamethyldisiloxane, 10.0 g of allyl acetate (acetic acid allylester) and 0.01 g of palladium supported on activated charcoal, in which the 0.1 g refers to the total weight of the charcoal and the palladium, is heated to boiling under reflux (approximately 105° C.) for 4 hours. The 1,1,1,3,3-pentamethyl-3-acetoxydisiloxane yield is quantitative.

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: This monomer was prepared in a manner similar to that described in Example 1. The reactants were γ-methacryloxypropyltrimethoxysilane (2 moles), 1,3-Bis(acetoxy)-1,1,3,3-TETRA(trimethylsiloxy)disilox ane (1 mole) and acetoxypentamethyldisiloxane (4 moles). This material is designated SM-16. This monomer was prepared in a manner similar to

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: This monomer was prepared in a manner similar to that described in Example 1. The reactants were γ-methacryloxypropyltrimethoxysilane (2 moles), 1,3-Bis(acetoxy)-1,1,3,3-TETRA(trimethylsiloxy)disiloxane (1 mole) and acetoxypentamethyldisiloxane (4 moles). This material is designated SM-16. This monomer was prepared in a manner similar to