titanium(III) trichloride

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: The mixture which was homogenised consisted of 119 g of titanium trichloride, 26 cm3 of butyl benzoate, 390 cm3 of toluene and 3 g of polystyrene ("Lustrex" HF 66). After operating the homogeniser at maximum power for 2.75 minutes, the contents of the flask had formed an immobile gel-like product and the temperature had risen to above 50° C. Homogenisation was terminated and 500 cm3 of toluene were added to assist in the transfer of the dispersed solid to a storage vessel. for 2.75 minutes the contents of the flask had formed an immobile gel-like product had risen to above 50° C Homogenisation was terminated 500 cm3 of toluene were added to assist in the transfer of the dispersed solid to a storage vessel

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: The mixture which was homogenised consisted of 119 g of titanium trichloride, 26 cm3 of butyl benzoate, 390 cm3 of toluene and 3 g of polystyrene ("Lustrex" HF 66). After operating the homogeniser at maximum power for 2.75 minutes, the contents of the flask had formed an immobile gel-like product and the temperature had risen to above 50° C. Homogenisation was terminated and 500 cm3 of toluene were added to assist in the transfer of the dispersed solid to a storage vessel. for 2.75 minutes the contents of the flask had formed an immobile gel-like product had risen to above 50° C Homogenisation was terminated 500 cm3 of toluene were added to assist in the transfer of the dispersed solid to a storage vessel

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: The mixture which was homogenised consisted of 119 g of titanium trichloride, 26 cm3 of butyl benzoate, 390 cm3 of toluene and 3 g of polystyrene ("Lustrex" HF 66). After operating the homogeniser at maximum power for 2.75 minutes, the contents of the flask had formed an immobile gel-like product and the temperature had risen to above 50° C. Homogenisation was terminated and 500 cm3 of toluene were added to assist in the transfer of the dispersed solid to a storage vessel. for 2.75 minutes the contents of the flask had formed an immobile gel-like product had risen to above 50° C Homogenisation was terminated 500 cm3 of toluene were added to assist in the transfer of the dispersed solid to a storage vessel

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Titanium trichloride composition (A) of 11.0 g was suspended in 55 ml of toluene and iodine and di-isoamyl ether were added in amounts to give a molar ratio of titanium trichloride composition (A)/I2 /di-isoamyl ether of 1.0/0.1/1.0 and then reacted at 80° C. for one hour to obtain titanium trichloride solid catalyst. This catalyst is referred to as titanium trichloride solid catalyst (II).

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Titanium trichloride composition (A) of 11.0 g was suspended in 55 ml of toluene and iodine and di-isoamyl ether were added in amounts to give a molar ratio of titanium trichloride composition (A)/I2 /di-isoamyl ether of 1.0/0.1/1.0 and then reacted at 80° C. for one hour to obtain titanium trichloride solid catalyst. This catalyst is referred to as titanium trichloride solid catalyst (II).

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 133 gms of the titanium trichloride were introduced into a stainless steel ball mill, 9 inches long and 5.1 inches diameter containing 685 stainless steel balls of diameter 0.5 inches. Hexamethylphosphoric triamide (HMPT) was added as a solid in an amount calculated to give a molecular ratio HMPT/titanium trichloride of 0.167. The contents of the mill were shaken manually to disperse the HMPT over the particles of TAC 131 and the mill was rotated for 22 hours at 45 rpm. A nitrogen atmosphere was maintained in the mill at all times.

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: The mixture which was homogenised consisted of 119 g of titanium trichloride, 26 cm3 of butyl benzoate, 390 cm3 of toluene and 3 g of polystyrene ("Lustrex" HF 66). After operating the homogeniser at maximum power for 2.75 minutes, the contents of the flask had formed an immobile gel-like product and the temperature had risen to above 50° C. Homogenisation was terminated and 500 cm3 of toluene were added to assist in the transfer of the dispersed solid to a storage vessel. for 2.75 minutes the contents of the flask had formed an immobile gel-like product had risen to above 50° C Homogenisation was terminated 500 cm3 of toluene were added to assist in the transfer of the dispersed solid to a storage vessel

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Titanium trichloride composition (A) of 11.0 g was suspended in 55 ml of toluene and iodine and di-isoamyl ether were added in amounts to give a molar ratio of titanium trichloride composition (A)/I2 /di-isoamyl ether of 1.0/0.1/1.0 and then reacted at 80° C. for one hour to obtain titanium trichloride solid catalyst. This catalyst is referred to as titanium trichloride solid catalyst (II).