sodium;(2E,4E)-hexa-2,4-dienoate

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Japanese Unexamined Patent Application Publication No. 54-163516 discloses a process for producing a sorbic acid. In this process, a polyester obtained from ketene and crotonaldehyde is decomposed with hydrochloric acid in the presence of, for example, a urea compound, the resulting decomposition reaction mixture is filtrated and rinsed to yield a crude sorbic acid, followed by addition of an aqueous sodium hydroxide solution to the crude sorbic acid to thereby yield an aqueous sodium sorbate solution, the aqueous sodium sorbate solution is treated with activated carbon, is neutralized and is cooled to thereby crystallize sorbic acid. is filtrated rinsed to yield a crude sorbic acid

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: As purification processes of sorbic acid or its salt, a treatment with activated carbon, recrystallization with water or with a mixture of water and an organic solvent, and distillation purification of a solution of sorbic acid or its salt in petroleum have been known. For example, Japanese Unexamined Patent Application Publication No. 54-163516 discloses a purification process. This process includes the steps of preparing a polyester from ketene and crotonaldehyde, decomposing the polyester with hydrochloric acid in the presence of, for example, a urea compound to yield a decomposition reaction mixture, separating the decomposition reaction mixture by filtration, and washing the residue to yield a crude sorbic acid, adding a sodium hydroxide aqueous solution to the crude sorbic acid to yield a sodium sorbate aqueous solution, treating the aqueous solution with activated carbon, neutralizing the treated solution, and cooling the neutralized solution to crystallize sorbic acid.

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: A related protocol is described in Japanese Unexamined Patent Application Publication No. 54-163516. Here, the polyester obtained from reacting crotonaldehyde and ketene is decomposed with hydrochloric acid in the presence of a urea compound. The resulting decomposition reaction mixture is filtered to yield crude sorbic acid. Aqueous sodium hydroxide solution is added to the crude sorbic acid to yield an aqueous sodium sorbate solution. The aqueous sodium sorbate solution is treated with activated carbon, neutralized, and cooled to crystallize the purified sorbic acid. The resulting decomposition reaction mixture is filtered to yield crude sorbic acid

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: For example, Japanese Unexamined Patent Application Publication No. 54-163516 discloses a process for preparing a crystalline sorbic acid. This process includes the steps of preparing a polyester from ketene and crotonaldehyde, decomposing the polyester with hydrochloric acid in the presence of, for example, a urea compound to yield a decomposition reaction mixture, separating the decomposition reaction mixture by filtration, and washing the residue to yield a crude sorbic acid, adding a sodium hydroxide aqueous solution to the crude sorbic acid to yield a sodium sorbate aqueous solution, treating the aqueous solution with activated carbon, neutralizing and cooling the treated solution to crystallize sorbic acid. Japanese Examined Patent Application Publication No. 44-26646 discloses a process for producing a crystalline sorbic acid. The process includes the steps of preparing a polyester from ketene and crotonaldehyde, decomposing the polyester with hydrochloric acid having a concentration of 35% by weight or more at temperatures ranging from room temperature to around the boiling point of the hydrochloric acid used, cooling the reaction mixture, separating a crude sorbic acid by filtration, washing the crude sorbic acid with water, putting the washed crude sorbic acid into water, heating and dissolving the sorbic acid to yield a solution, adding activated carbon to the solution, boiling the mixture, and filtering the mixture while heating, and gradually cooling the resulting filtrate to yield a crystalline sorbic acid.

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: To 135 parts of the above-prepared polyester, 110 parts of a concentrated hydrochloric acid was added, and the resulting mixture was heated to 80° C. to decompose the polyester. The resulting mixture was separated by filtration, and was washed to yield 123 parts of a crude sorbic acid. A sodium hydroxide aqueous solution was added to the crude sorbic acid to yield a sodium sorbate aqueous solution, and to the solution 6 parts of active carbon was added, and the resulting mixture was stirred for 30 minutes. The mixture was filtrated to remove the active carbon, and a neutralization amount of a concentrated hydrochloric acid was added to the filtrate and the mixture was cooled to precipitate sorbic acid. The precipitated sorbic acid was separated by filtration, was washed, and was dried in vacuo to yield 114 parts of sorbic acid. The yield of sorbic acid was 84.7% on the basis of the polyester.

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: Japanese Unexamined Patent Application Publication No. 54-163516 discloses a process for producing a sorbic acid. In this process, a polyester obtained from ketene and crotonaldehyde is decomposed with hydrochloric acid in the presence of, for example, a urea compound, the resulting decomposition reaction mixture is filtrated and rinsed to yield a crude sorbic acid, followed by addition of an aqueous sodium hydroxide solution to the crude sorbic acid to thereby yield an aqueous sodium sorbate solution, the aqueous sodium sorbate solution is treated with activated carbon, is neutralized and is cooled to thereby crystallize sorbic acid. is filtrated rinsed to yield a crude sorbic acid