表示可能な構造データがありません
CC(C)(C)OC(=O)CCCCCCCCCCCCCCBr製品情報
tert-butyl 15-bromopentadecanoate (CAS 905302-64-9) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
想定用途
専門的研究・工業用途限定
データベース ID 58079429
安全上の注意
For professional research and industrial use only. Review the supplier safety data sheet before handling.
合成データ
11 反応 · 11 文献
反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-51c43d0c90e3490593a2f4460f28c1bb反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: 5-Hydroxy-isophthalic acid dimethyl ester (420 mg, 2 mmol), 15-bromo-pentadecanoic acid tert-butyl ester (755 mg, 2 mmol) and K2CO3 (415 mg, 3 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed by TLC (4:1 heptane/AcOEt), which indicated reaction completion after 6 h. The sample was concentrated to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield a white crystalline solid (1.0 g, 100%). refluxed under N2 reaction completion after 6 h The sample was concentrated AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
ソース ID: ord-069f7f938d00444aae531b478972dc9d反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: 15-Bromo-pentadecanoic acid tert-butyl ester (598 mg, 1.59 mmol), 4-hydroxy isophthalic acid 3-tert-butyl ester 1-methyl ester (400 mg, 1.59 mmol) and K2CO3 (329 mg, 2.38 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed via TLC (4:1 heptane/AcOEt). After 13 h the sample was concentrated under vacuum to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield an oil (841 mg, 97%). refluxed under N2 After 13 h the sample was concentrated under vacuum AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
ソース ID: ord-73f4cdf9bcdd48268188b0ef2f94e35c反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: 15-Bromo-pentadecanoic acid tert-butyl ester (598 mg, 1.59 mmol), 4-hydroxy isophthalic acid 3-tert-butyl ester 1-methyl ester (400 mg, 1.59 mmol) and K2CO3 (329 mg, 2.38 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed via TLC (4:1 heptane/AcOEt). After 13 h the sample was concentrated under vacuum to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield an oil (841 mg, 97%). refluxed under N2 After 13 h the sample was concentrated under vacuum AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
ソース ID: ord-73f4cdf9bcdd48268188b0ef2f94e35c反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: 5-Hydroxy-isophthalic acid dimethyl ester (420 mg, 2 mmol), 15-bromo-pentadecanoic acid tert-butyl ester (755 mg, 2 mmol) and K2CO3 (415 mg, 3 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed by TLC (4:1 heptane/AcOEt), which indicated reaction completion after 6 h. The sample was concentrated to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield a white crystalline solid (1.0 g, 100%). refluxed under N2 reaction completion after 6 h The sample was concentrated AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
ソース ID: ord-2ac38b540b7847bfab8389a7a3bb1c02反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: 15-Bromo-pentadecanoic acid tert-butyl ester (598 mg, 1.59 mmol), 4-hydroxy isophthalic acid 3-tert-butyl ester 1-methyl ester (400 mg, 1.59 mmol) and K2CO3 (329 mg, 2.38 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed via TLC (4:1 heptane/AcOEt). After 13 h the sample was concentrated under vacuum to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield an oil (841 mg, 97%). refluxed under N2 After 13 h the sample was concentrated under vacuum AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
ソース ID: ord-5f9ad986631c45cdbf6d5fea2d3431d0反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-51c43d0c90e3490593a2f4460f28c1bb反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: 5-Hydroxy-isophthalic acid dimethyl ester (420 mg, 2 mmol), 15-bromo-pentadecanoic acid tert-butyl ester (755 mg, 2 mmol) and K2CO3 (415 mg, 3 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed by TLC (4:1 heptane/AcOEt), which indicated reaction completion after 6 h. The sample was concentrated to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield a white crystalline solid (1.0 g, 100%). refluxed under N2 reaction completion after 6 h The sample was concentrated AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
ソース ID: ord-069f7f938d00444aae531b478972dc9d反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: 15-Bromo-pentadecanoic acid tert-butyl ester (598 mg, 1.59 mmol), 4-hydroxy isophthalic acid 3-tert-butyl ester 1-methyl ester (400 mg, 1.59 mmol) and K2CO3 (329 mg, 2.38 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed via TLC (4:1 heptane/AcOEt). After 13 h the sample was concentrated under vacuum to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield an oil (841 mg, 97%). refluxed under N2 After 13 h the sample was concentrated under vacuum AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
ソース ID: ord-73f4cdf9bcdd48268188b0ef2f94e35c反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: 5-Hydroxy-isophthalic acid dimethyl ester (420 mg, 2 mmol), 15-bromo-pentadecanoic acid tert-butyl ester (755 mg, 2 mmol) and K2CO3 (415 mg, 3 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed by TLC (4:1 heptane/AcOEt), which indicated reaction completion after 6 h. The sample was concentrated to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield a white crystalline solid (1.0 g, 100%). refluxed under N2 reaction completion after 6 h The sample was concentrated AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
ソース ID: ord-2ac38b540b7847bfab8389a7a3bb1c02反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: 15-Bromo-pentadecanoic acid tert-butyl ester (598 mg, 1.59 mmol), 4-hydroxy isophthalic acid 3-tert-butyl ester 1-methyl ester (400 mg, 1.59 mmol) and K2CO3 (329 mg, 2.38 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed via TLC (4:1 heptane/AcOEt). After 13 h the sample was concentrated under vacuum to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield an oil (841 mg, 97%). refluxed under N2 After 13 h the sample was concentrated under vacuum AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
ソース ID: ord-5f9ad986631c45cdbf6d5fea2d3431d0PubChem References
化合物の公開データベース記録に掲載された情報源です。
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