2-benzylcyclohexan-1-one

反応条件: temp:0.00; pressure:0.00; stir:

反応条件: temp:0.00; pressure:0.00; stir:

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: A mixture of 1-(1-pyrrolidinyl)cyclohexane (85.4 g) and benzyl chloride (100 ml) in dioxane (400 ml) was heated under reflux for 23 hours under nitrogen. Water (100 ml) was then added and the brown oil was distilled to give (2RS)-2-phenylmethylcyclohexanone (47.1 g). was heated under reflux for 23 hours under nitrogen the brown oil was distilled

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 18.83 g (0.1 mole) of 2-benzylcyclohexan-1-one and 9.0 g (0.1 mole) of N-methoxycarbonyl hydrazine are dissolved in 100 cm3 of anhydrous ethanol, and the solution is boiled for 2 hours. Then it is cooled, and the separated crystals are filtered off. 18.2 g (96.9%) of the named compound are obtained. Then it is cooled the separated crystals are filtered off

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 18.83 g (0.1 mole) of 2-benzylcyclohexan-1-one and 9.0 g (0.1 mole) of N-methoxycarbonyl hydrazine are dissolved in 100 cm3 of anhydrous ethanol, and the solution is boiled for 2 hours. Then it is cooled, and the separated crystals are filtered off. 18.2 g (96.9%) of the named compound are obtained. Then it is cooled the separated crystals are filtered off

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: A mixture of 1-(1-pyrrolidinyl)cyclohexane (85.4 g) and benzyl chloride (100 ml) in dioxane (400 ml) was heated under reflux for 23 hours under nitrogen. Water (100 ml) was then added and the brown oil was distilled to give (2RS)-2-phenylmethylcyclohexanone (47.1 g). was heated under reflux for 23 hours under nitrogen the brown oil was distilled

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: A mixture of 1-(1-pyrrolidinyl)cyclohexane (85.4 g) and benzyl chloride (100 ml) in dioxane (400 ml) was heated under reflux for 23 hours under nitrogen. Water (100 ml) was then added and the brown oil was distilled to give (2RS)-2-phenylmethylcyclohexanone (47.1 g). was heated under reflux for 23 hours under nitrogen the brown oil was distilled

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: 18.83 g (0.1 mole) of 2-benzylcyclohexan-1-one and 9.0 g (0.1 mole) of N-methoxycarbonyl hydrazine are dissolved in 100 cm3 of anhydrous ethanol, and the solution is boiled for 2 hours. Then it is cooled, and the separated crystals are filtered off. 18.2 g (96.9%) of the named compound are obtained. Then it is cooled the separated crystals are filtered off

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: The chlorination of 2-benzylcyclohexanone takes place in a manner similar to that described above for the preparation of 2-tert-butyl-6-chloro-cyclohexanone. The title compound is reacted as a crude product without further characterization.

反応条件: temp:0.00; pressure:0.00; stir:

反応条件: temp:0.00; pressure:0.00; stir:

反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

実験手順: The chlorination of 2-benzylcyclohexanone takes place in a manner similar to that described above for the preparation of 2-tert-butyl-6-chloro-cyclohexanone. The title compound is reacted as a crude product without further characterization.