表示可能な構造データがありません
CC(C)N(CC1=CC=C(C=C1)Br)C(C)C製品情報
N-[(4-bromophenyl)methyl]-N-propan-2-ylpropan-2-amine (CAS 98816-61-6) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
想定用途
専門的研究・工業用途限定
データベース ID 598770
安全上の注意
For professional research and industrial use only. Review the supplier safety data sheet before handling.
合成データ
10 反応 · 10 文献
反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-1db7147b95684f38b3bdf16a977d8ee7反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of N-(4-bromobenzyl)-N,N-diisopropylamine (2.3 g) in THF (10 ml) was added dropwise at −78° C. n-BuLi (1.6 mmol/ml hexane solution, 3.8 ml). Ten minutes later, N,O-dimethyl-N-(1-trityl-piperidine-4-carbonyl)hydroxylamine (1.5 g) in THF (20 ml) was added dropwise to the mixture, and the mixture was stirred at the same temperature for 30 minutes. To the mixture was added ammonium chloride aqueous solution, and the mixture was extracted with ethyl acetate. The extract was washed with water, dried (MgSO4) and concentrated to give the title compound (5.0 g). the mixture was extracted with ethyl acetate The extract was washed with water dried (MgSO4) concentrated
ソース ID: ord-4e0682a8042f420a89b225e795ace753反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of N-(4-bromobenzyl)-N,N-diisopropylamine (2.3 g) in THF (10 ml) was added dropwise at −78° C. n-BuLi (1.6 mmol/ml hexane solution, 3.8 ml). Ten minutes later, N,O-dimethyl-N-(1-trityl-piperidine-4-carbonyl)hydroxylamine (1.5 g) in THF (20 ml) was added dropwise to the mixture, and the mixture was stirred at the same temperature for 30 minutes. To the mixture was added ammonium chloride aqueous solution, and the mixture was extracted with ethyl acetate. The extract was washed with water, dried (MgSO4) and concentrated to give the title compound (5.0 g). the mixture was extracted with ethyl acetate The extract was washed with water dried (MgSO4) concentrated
ソース ID: ord-4e0682a8042f420a89b225e795ace753反応条件: temp:80.01; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: A mixture of 4-bromobenzylbromide (5.0 g), N,N-diisopropylamine (7.85 ml) and potassium carbonate (2.76 g) in dimethylformamide (50 ml) was stirred at 80° C. for 2 hours. To the mixture was added water, and the mixture was extracted with ether. The extract was washed with water, dried (MgSO4) and concentrated to give the title compound (5.0 g). the mixture was extracted with ether The extract was washed with water dried (MgSO4) concentrated
ソース ID: ord-0947629a38f245a280dfe00ef647a3cd反応条件: temp:80.01; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: A mixture of 4-bromobenzylbromide (5.0 g), N,N-diisopropylamine (7.85 ml) and potassium carbonate (2.76 g) in dimethylformamide (50 ml) was stirred at 80° C. for 2 hours. To the mixture was added water, and the mixture was extracted with ether. The extract was washed with water, dried (MgSO4) and concentrated to give the title compound (5.0 g). the mixture was extracted with ether The extract was washed with water dried (MgSO4) concentrated
ソース ID: ord-0947629a38f245a280dfe00ef647a3cd反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of N-(4-bromobenzyl)-N,N-diisopropylamine (2.3 g) in THF (10 ml) was added dropwise at −78° C. n-BuLi (1.6 mmol/ml hexane solution, 3.8 ml). Ten minutes later, N,O-dimethyl-N-(1-trityl-piperidine-4-carbonyl)hydroxylamine (1.5 g) in THF (20 ml) was added dropwise to the mixture, and the mixture was stirred at the same temperature for 30 minutes. To the mixture was added ammonium chloride aqueous solution, and the mixture was extracted with ethyl acetate. The extract was washed with water, dried (MgSO4) and concentrated to give the title compound (5.0 g). the mixture was extracted with ethyl acetate The extract was washed with water dried (MgSO4) concentrated
ソース ID: ord-4e0682a8042f420a89b225e795ace753反応条件: temp:80.01; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: A mixture of 4-bromobenzylbromide (5.0 g), N,N-diisopropylamine (7.85 ml) and potassium carbonate (2.76 g) in dimethylformamide (50 ml) was stirred at 80° C. for 2 hours. To the mixture was added water, and the mixture was extracted with ether. The extract was washed with water, dried (MgSO4) and concentrated to give the title compound (5.0 g). the mixture was extracted with ether The extract was washed with water dried (MgSO4) concentrated
ソース ID: ord-0947629a38f245a280dfe00ef647a3cd反応条件: temp:0.00; pressure:0.00; stir:
ソース ID: ord-1db7147b95684f38b3bdf16a977d8ee7反応条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: To a solution of N-(4-bromobenzyl)-N,N-diisopropylamine (2.3 g) in THF (10 ml) was added dropwise at −78° C. n-BuLi (1.6 mmol/ml hexane solution, 3.8 ml). Ten minutes later, N,O-dimethyl-N-(1-trityl-piperidine-4-carbonyl)hydroxylamine (1.5 g) in THF (20 ml) was added dropwise to the mixture, and the mixture was stirred at the same temperature for 30 minutes. To the mixture was added ammonium chloride aqueous solution, and the mixture was extracted with ethyl acetate. The extract was washed with water, dried (MgSO4) and concentrated to give the title compound (5.0 g). the mixture was extracted with ethyl acetate The extract was washed with water dried (MgSO4) concentrated
ソース ID: ord-4e0682a8042f420a89b225e795ace753反応条件: temp:80.01; pressure:0.00; stir:; See reaction.notes.procedure_details.
実験手順: A mixture of 4-bromobenzylbromide (5.0 g), N,N-diisopropylamine (7.85 ml) and potassium carbonate (2.76 g) in dimethylformamide (50 ml) was stirred at 80° C. for 2 hours. To the mixture was added water, and the mixture was extracted with ether. The extract was washed with water, dried (MgSO4) and concentrated to give the title compound (5.0 g). the mixture was extracted with ether The extract was washed with water dried (MgSO4) concentrated
ソース ID: ord-0947629a38f245a280dfe00ef647a3cdPubChem References
化合物の公開データベース記録に掲載された情報源です。
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